PMID- 22118848 OWN - NLM STAT- MEDLINE DCOM- 20120425 LR - 20131121 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 199-200 DP - 2012 Jan 15 TI - Separation of n-hexane/acetone mixtures by pervaporation using high density polyethylene/ethylene propylene diene terpolymer rubber blend membranes. PG - 336-42 LID - 10.1016/j.jhazmat.2011.11.028 [doi] AB - Polymer membranes were prepared by blending high density polyethylene (HDPE) with ethylene propylene diene terpolymer rubber (EPDM). These blend membranes were evaluated for the selective separation of n-hexane from acetone. The flux and selectivity of the membranes were determined both as a function of the blend composition and feed mixture composition. Results showed that polymer blending method could be very useful to develop new membranes with improved selectivity. Pervaporation properties could be optimized by adjusting the blend composition. The effects of blend ratio, feed composition, and penetrant size on the pervaporation process were analyzed. The permeation properties have been explained on the basis of interaction between the membrane and solvents and blend morphology. Flux increases with increasing alkane content in the feed composition. CI - Copyright (c) 2011 Elsevier B.V. All rights reserved. FAU - Kumar, P V Anil AU - Kumar PV AD - School of Chemical Sciences, Mahatma Gandhi University, Priyadarshini Hills P.O., Kottayam, Kerala 686 560, India. anilmgu@gmail.com FAU - Anilkumar, S AU - Anilkumar S FAU - Varughese, K T AU - Varughese KT FAU - Thomas, Sabu AU - Thomas S LA - eng PT - Journal Article DEP - 20111111 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Alkenes) RN - 0 (Hexanes) RN - 0 (Membranes, Artificial) RN - 1364PS73AF (Acetone) RN - 2DDG612ED8 (n-hexane) RN - 9002-88-4 (Polyethylene) RN - 9006-04-6 (Rubber) RN - AUG1H506LY (propylene) SB - IM MH - Acetone/*isolation & purification MH - Alkenes/*chemistry MH - Hexanes/*isolation & purification MH - *Membranes, Artificial MH - Microscopy, Electron, Scanning MH - Polyethylene/*chemistry MH - Rubber/*chemistry EDAT- 2011/11/29 06:00 MHDA- 2012/04/26 06:00 CRDT- 2011/11/29 06:00 PHST- 2011/06/15 00:00 [received] PHST- 2011/11/01 00:00 [revised] PHST- 2011/11/05 00:00 [accepted] PHST- 2011/11/29 06:00 [entrez] PHST- 2011/11/29 06:00 [pubmed] PHST- 2012/04/26 06:00 [medline] AID - S0304-3894(11)01394-X [pii] AID - 10.1016/j.jhazmat.2011.11.028 [doi] PST - ppublish SO - J Hazard Mater. 2012 Jan 15;199-200:336-42. doi: 10.1016/j.jhazmat.2011.11.028. Epub 2011 Nov 11.