PMID- 22133910 OWN - NLM STAT- MEDLINE DCOM- 20120828 LR - 20171116 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 86 IP - 7 DP - 2012 Feb TI - Concentrations of organochlorine pesticides and 2,4,6-trichloroanisole in cork bark. PG - 754-8 LID - 10.1016/j.chemosphere.2011.11.009 [doi] AB - Organochlorine pesticides are persistent lipophilic organic pollutants and tend to accumulate in growing plants. During growth, cork is in contact with the open air for long periods (9-12 years). Owing to the previous widespread use of organochlorine pesticides and their high persistence in the environment, there is a risk that residues of such pesticides may be present in cork. In this study, the concentrations of 14 organochlorine pesticides-all of which are indicators of environmental pollution-were analyzed in cork bark samples from three regions in Spain and one in Portugal. In addition, the concentrations of 2,4,6-trichlorophenol (TCP) and 2,4,6-trichloroanisole (TCA) were also analyzed. Our results show only very low concentrations of lindane, gamma-HCH (<2.6 ng g(-1)) and its byproducts alpha-HCH (<3.5 ng g(-1)) and beta-HCH (<0.6 ng g(-1)). Among the DDT and its metabolites, only two were found: p,p'-DDT was found in a cork sample from Extremadura (0.1 ng g(-1)) and p,p'-DDE was present at a maximum concentration of 2.9 ng g(-1) in a cork sample from Castile-La Mancha. However, all concentrations were well below the legal limit established by Regulation (EC) No. 396/2005 (10 ng g(-1) in foodstuffs). We can conclude, therefore, that the cork samples we studied complied with food safety standards. CI - Copyright (c) 2011 Elsevier Ltd. All rights reserved. FAU - Olivella, M Angels AU - Olivella MA AD - University of Girona, Department of Chemistry, Campus Montilivi s/n, 17071 Girona, Spain. angels.olivella@udg.edu FAU - Caixach, Josep AU - Caixach J FAU - Planas, Carles AU - Planas C FAU - Oliveras, Anna AU - Oliveras A FAU - Jove, Patricia AU - Jove P LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20111130 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Anisoles) RN - 0 (Chlorophenols) RN - 0 (Environmental Pollutants) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticide Residues) RN - 31O3X41254 (2,4,6-trichloroanisole) RN - MHS8C5BAUZ (2,4,6-trichlorophenol) SB - IM MH - Anisoles/*analysis MH - Chlorophenols/analysis MH - Environmental Pollutants/*analysis MH - Food Safety MH - Hydrocarbons, Chlorinated/*analysis MH - Pesticide Residues/*analysis MH - Plant Bark/*chemistry MH - Quercus/*chemistry MH - Wine EDAT- 2011/12/03 06:00 MHDA- 2012/08/29 06:00 CRDT- 2011/12/03 06:00 PHST- 2011/10/08 00:00 [received] PHST- 2011/10/28 00:00 [revised] PHST- 2011/11/06 00:00 [accepted] PHST- 2011/12/03 06:00 [entrez] PHST- 2011/12/03 06:00 [pubmed] PHST- 2012/08/29 06:00 [medline] AID - S0045-6535(11)01261-6 [pii] AID - 10.1016/j.chemosphere.2011.11.009 [doi] PST - ppublish SO - Chemosphere. 2012 Feb;86(7):754-8. doi: 10.1016/j.chemosphere.2011.11.009. Epub 2011 Nov 30.