PMID- 22252273
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20120612
LR  - 20120215
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 41
IP  - 9
DP  - 2012 Mar 7
TI  - Mono- and dinuclear ruthenium(II) 1,6,7,12-tetraazaperylene complexes.
PG  - 2788-97
LID - 10.1039/c2dt11805j [doi]
AB  - We report the synthesis of free 1,6,7,12-tetraazaperylene (tape). Tape was 
      obtained from 1,1'-bis-2,7-naphthyridine by potassium promoted cyclization 
      followed by oxidation with air. Mono- and dinuclear ruthenium(II) 
      1,6,7,12-tetraazaperylene complexes of the general formulas 
      [Ru(L-L)(2)(tape)](PF(6))(2), [1](PF(6))(2)-[5](PF(6))(2), and 
      [Ru(L-L)(2)(2)(mu-tape)](PF(6))(4), [6](PF(6))(4)-[10](PF(6))(4), withL-L = 
      phen, bpy, dmbpy (4,4'-dimethyl-2,2'-bipyridine), dtbbpy 
      (4,4'-ditertbutyl-2,2'-bipyridine) and tmbpy 
      (4,4'5,5'-tetramethyl-2,2'-bipyridine), respectively, were synthesized. The 
      X-ray structures of tape.2CHCl(3) and the mononuclear complexes 
      [Ru(bpy)(2)(tape)](PF(6))(2).0.5CH(3)CN.0.5toluene, 
      [Ru(dmbpy)(2)(tape)](PF(6))(2).2toluene and 
      [Ru(dtbbpy)(2)(tape)](PF(6))(2).3acetone.0.5H(2)O were solved. The UV-vis 
      absorption spectra and the electrochemical behavior of the ruthenium(ii) tape 
      complexes were explored and compared with the data of the analogous 
      dibenzoeilatin (dbneil), 2,2'-bipyrimidine (bpym) and 
      tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazin (tpphz) species.
FAU - Brietzke, Thomas
AU  - Brietzke T
AD  - Institute for Chemistry, Inorganic Chemistry, University of Potsdam, Golm, 
      Germany.
FAU - Mickler, Wulfhard
AU  - Mickler W
FAU - Kelling, Alexandra
AU  - Kelling A
FAU - Holdt, Hans-Jurgen
AU  - Holdt HJ
LA  - eng
PT  - Journal Article
DEP - 20120117
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2012/01/19 06:00
MHDA- 2012/01/19 06:01
CRDT- 2012/01/19 06:00
PHST- 2012/01/19 06:00 [entrez]
PHST- 2012/01/19 06:00 [pubmed]
PHST- 2012/01/19 06:01 [medline]
AID - 10.1039/c2dt11805j [doi]
PST - ppublish
SO  - Dalton Trans. 2012 Mar 7;41(9):2788-97. doi: 10.1039/c2dt11805j. Epub 2012 Jan 
      17.