PMID- 22268361
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20121015
LR  - 20161018
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 29
IP  - 10
DP  - 2011 Oct
TI  - [Simultaneous determination of chromium speciation in cosmetics using 
      reversed-phase ion-pair chromatography-inductively coupled plasma mass 
      spectrometry].
PG  - 1027-30
AB  - A method was developed to determine chromium speciation simultaneously in 
      cosmetics using reversed-phase ion-pair chromatography (RP-IPC) with inductively 
      coupled plasma mass spectrometry (ICP-MS). After the extraction with disodium 
      ethylenediaminetetraacetate(EDTA) in a water bath, the sample was separated on an 
      XDB C18 column with the mobile phase of 5% (v/v) methanol-2. 0 mmol/L 
      tetrabutylammonium (TBA) (pH 6.0), the flow rate of 1.0 mL/min and the injection 
      volume of 100 microL. The collision cell technology was applied to eliminate the 
      mass interferences of 40Ar12 C+ and 35 C16O1 H+ in the analysis of 52 Cr+. The 
      separation was achieved within 5 min. The recoveries of Cr( III) and Cr( VI) 
      ranged from 82.7% to 107. 2% with the relative standard deviations (RSDs) less 
      than 5. 62% (n = 6) with the spiked amounts of 0.01 -0.50 microg in different 
      kinds of cosmetic samples. The developed method has the advantages of simplicity, 
      sensitivity and good reproducibility, and can be used for the simultaneous 
      determination of Cr(III) and Cr( VI) in cosmetics.
FAU - Pang, Yanhu
AU  - Pang Y
AD  - Liaoning Entry-Exit Inspection and Quarantine Bureau, Dalian 116001, China. 
      cindy_gl@eyou.com
FAU - Liu, Mingyang
AU  - Liu M
FAU - Liu, Shuyan
AU  - Liu S
FAU - Dong, Zhenlin
AU  - Dong Z
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
EDAT- 2012/01/25 06:00
MHDA- 2012/01/25 06:01
CRDT- 2012/01/25 06:00
PHST- 2012/01/25 06:00 [entrez]
PHST- 2012/01/25 06:00 [pubmed]
PHST- 2012/01/25 06:01 [medline]
PST - ppublish
SO  - Se Pu. 2011 Oct;29(10):1027-30.