PMID- 22284489
OWN - NLM
STAT- MEDLINE
DCOM- 20120622
LR  - 20161125
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 89
DP  - 2012 Jan 30
TI  - Analysis of endocrine disrupting compounds, pharmaceuticals and personal care 
      products in sewage sludge by gas chromatography-mass spectrometry.
PG  - 258-63
LID - 10.1016/j.talanta.2011.12.023 [doi]
AB  - Endocrine disrupting compounds (EDCs) and pharmaceuticals and personal care 
      products (PPCPs) have been acknowledged as emerging pollutants due to widespread 
      contamination in environment. A rapid and reliable analytical method, based on 
      ultrasonic extraction, clean up on Envi-carb cartridge, derivatized with 
      N-tert-butyldimethylsilyl-N-methyltrifluoroacetamide (MTBSTFA), and analyzed by 
      gas chromatography-mass spectrometry (GC-MS), was developed for determination of 
      4 EDCs (bisphenol A, estrone, nonylphenol and octylphenol) and 10 PPCPs 
      (acetylsalicylic acid, carbamazepine, clofibric acid, diclofenac, gemfibrozil, 
      ibuprofen, ketoprofen, naproxen, paracetamol and triclosan) in sewage sludge. 
      Mean recoveries of the target analytes, at different spike levels (40, 300 and 
      2000 ng/g), ranged from 57.9% to 103.1%. Relative standard deviations (RSDs) were 
      in the range of 1.3-9.5% at different spiked levels. The limit of quantification 
      (LOQ) ranged from 4.7 to 39 ng/g. The method was applied to sewage sludge samples 
      from sewage treatment plants (STPs) in southern California. High concentrations 
      of PPCPs and EDCs were found in sewage sludge, ranging from 1502 to 5327 ng/g dry 
      weight. Appropriate disposal of sewage sludge was required to avoid secondary 
      contamination.
CI  - Copyright (c) 2011 Elsevier B.V. All rights reserved.
FAU - Yu, Yong
AU  - Yu Y
AD  - Department of Environmental Sciences, University of California, Riverside, CA 
      92521, USA. yuyong.env@gmail.com
FAU - Wu, Laosheng
AU  - Wu L
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20111217
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Acetamides)
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Endocrine Disruptors)
RN  - 0 (Fluoroacetates)
RN  - 0 (Organosilicon Compounds)
RN  - 0 (Phenols)
RN  - 0 (Prescription Drugs)
RN  - 0 (Sewage)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (octylphenol)
RN  - 2DI9HA706A (Estrone)
RN  - 77377-52-7 (N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide)
RN  - 79F6A2ILP5 (nonylphenol)
RN  - E5R8Z4G708 (Trifluoroacetic Acid)
RN  - MLT3645I99 (bisphenol A)
SB  - IM
MH  - Acetamides
MH  - Benzhydryl Compounds
MH  - Endocrine Disruptors/*analysis
MH  - Estrone/analysis
MH  - Fluoroacetates
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Humans
MH  - Limit of Detection
MH  - Organosilicon Compounds/chemistry
MH  - Phenols/analysis
MH  - Prescription Drugs/analysis
MH  - Sewage/*chemistry
MH  - Solid Phase Extraction
MH  - Sonication
MH  - Trifluoroacetic Acid/chemistry
MH  - Water Pollutants, Chemical/*analysis
EDAT- 2012/01/31 06:00
MHDA- 2012/06/23 06:00
CRDT- 2012/01/31 06:00
PHST- 2011/11/05 00:00 [received]
PHST- 2011/12/12 00:00 [revised]
PHST- 2011/12/12 00:00 [accepted]
PHST- 2012/01/31 06:00 [entrez]
PHST- 2012/01/31 06:00 [pubmed]
PHST- 2012/06/23 06:00 [medline]
AID - S0039-9140(11)01091-5 [pii]
AID - 10.1016/j.talanta.2011.12.023 [doi]
PST - ppublish
SO  - Talanta. 2012 Jan 30;89:258-63. doi: 10.1016/j.talanta.2011.12.023. Epub 2011 Dec 
      17.