PMID- 22323275 OWN - NLM STAT- MEDLINE DCOM- 20120629 LR - 20200930 IS - 1521-4095 (Electronic) IS - 0935-9648 (Linking) VI - 24 IP - 10 DP - 2012 Mar 8 TI - Ultrafast polymerization inhibition by stimulated emission depletion for three-dimensional nanolithography. PG - OP65-9 LID - 10.1002/adma.201103758 [doi] AB - To identify the depletion mechanism in the stimulated-emission-depletion (STED) inspired photoresist composed of a ketocoumarin photoinitiator in pentaerythritol tetraacrylate, we perform lithography with pulsed excitation and tunable delayed depletion. A fast component can unambiguously be assigned to stimulated emission. Our results allow the systematical optimization of the conditions in next-generation STED direct-laser-writing optical lithography. CI - Copyright (c) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. FAU - Fischer, Joachim AU - Fischer J AD - Karlsruhe Institute of Technology, Wolfgang-Gaede-Strasse 1, Karlsruhe, Germany. joachim.fischer@kit.edu FAU - Wegener, Martin AU - Wegener M LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120210 PL - Germany TA - Adv Mater JT - Advanced materials (Deerfield Beach, Fla.) JID - 9885358 SB - IM MH - Kinetics MH - Nanotechnology/*methods MH - Optical Phenomena MH - *Polymerization MH - Printing/*methods EDAT- 2012/02/11 06:00 MHDA- 2012/06/30 06:00 CRDT- 2012/02/11 06:00 PHST- 2011/09/30 00:00 [received] PHST- 2011/12/14 00:00 [revised] PHST- 2012/02/11 06:00 [entrez] PHST- 2012/02/11 06:00 [pubmed] PHST- 2012/06/30 06:00 [medline] AID - 10.1002/adma.201103758 [doi] PST - ppublish SO - Adv Mater. 2012 Mar 8;24(10):OP65-9. doi: 10.1002/adma.201103758. Epub 2012 Feb 10.