PMID- 22354763 OWN - NLM STAT- MEDLINE DCOM- 20120810 LR - 20120413 IS - 1521-3927 (Electronic) IS - 1022-1336 (Linking) VI - 33 IP - 8 DP - 2012 Apr 23 TI - Hierarchical mesoporous silica fabricated from an ABC triblock terpolymer as a single template. PG - 678-82 LID - 10.1002/marc.201100857 [doi] AB - Hierarchical mesoporous silicas containing two kinds of mesoporous size are successfully synthesized using the simple evaporation-induced self-assembly (EISA) strategy. Two blocks of hydrophobic segments (PE and PCL) in the poly(ethylene-block-ethylene oxide-block-ϵ-caprolactone) (PE-PEO-PCL) triblock copolymer are involved in the two types of mesopore after calcination, the PE segment being attributed to the face-centered cubic (fcc) morphology (spherical pores) and the PCL segment attributed to the tetragonal cylinder structure (cylindrical pores). CI - Copyright (c) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. FAU - Li, Jheng-Guang AU - Li JG AD - Department of Materials and Optoelectronic Science, Center for Nanoscience and Nanotechnology, National Sun Yat-Sen University, Kaohsiung, 804, Taiwan. FAU - Lin, Ruei-Bin AU - Lin RB FAU - Kuo, Shiao-Wei AU - Kuo SW LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120221 PL - Germany TA - Macromol Rapid Commun JT - Macromolecular rapid communications JID - 9888239 RN - 0 (Polyesters) RN - 0 (Polymers) RN - 0 (polyethylene oxide-polycaprolactone copolymer) RN - 7631-86-9 (Silicon Dioxide) RN - 9002-88-4 (Polyethylene) SB - IM MH - Hydrophobic and Hydrophilic Interactions MH - Polyesters/chemistry MH - Polyethylene/chemistry MH - Polymers/*chemistry MH - Porosity MH - Scattering, Small Angle MH - Silicon Dioxide/*chemistry MH - X-Ray Diffraction EDAT- 2012/02/23 06:00 MHDA- 2012/08/11 06:00 CRDT- 2012/02/23 06:00 PHST- 2011/12/19 00:00 [received] PHST- 2012/02/23 06:00 [entrez] PHST- 2012/02/23 06:00 [pubmed] PHST- 2012/08/11 06:00 [medline] AID - 10.1002/marc.201100857 [doi] PST - ppublish SO - Macromol Rapid Commun. 2012 Apr 23;33(8):678-82. doi: 10.1002/marc.201100857. Epub 2012 Feb 21.