PMID- 22387324 OWN - NLM STAT- MEDLINE DCOM- 20120920 LR - 20131121 IS - 1095-8630 (Electronic) IS - 0301-4797 (Linking) VI - 101 DP - 2012 Jun 30 TI - Photocatalytic degradation of acridine dyes using anatase and rutile TiO2. PG - 1-6 LID - 10.1016/j.jenvman.2012.02.014 [doi] AB - The adsorption and photodegradation of acridine orange (AO) and acriflavine (AF) dyes on two mesoporous titania crystalline phases, anatase and rutile, were experimentally studied. Anatase and rutile were characterized by nitrogen adsorption, electron scanning and transmission microscopy, and X-ray diffraction. The adsorption capacity of rutile was higher than that of anatase, while the reverse is observed for photodegradation of both dyes. The adsorption of AF on both adsorbents was higher than that of AO, which was related with the smaller size of AF molecules compared with those of AO, therefore the access of AF to the adsorption sites is favored. CI - Copyright (c) 2012. Published by Elsevier Ltd. FAU - Zubieta, C E AU - Zubieta CE AD - IFISUR, Universidad Nacional del Sur, Av. Alem 1253, Bahia Blanca, Argentina. FAU - Messina, P V AU - Messina PV FAU - Schulz, P C AU - Schulz PC LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120302 PL - England TA - J Environ Manage JT - Journal of environmental management JID - 0401664 RN - 0 (Fluorescent Dyes) RN - 0 (Solutions) RN - 0 (Water Pollutants, Chemical) RN - 15FIX9V2JP (titanium dioxide) RN - 1T3A50395T (Acriflavine) RN - D1JT611TNE (Titanium) RN - F30N4O6XVV (Acridine Orange) RN - N762921K75 (Nitrogen) SB - IM MH - Acridine Orange/*chemistry MH - Acriflavine/*chemistry MH - Adsorption MH - Fluorescent Dyes/*chemistry MH - Microscopy, Electron, Scanning MH - Nitrogen/chemistry MH - *Photochemical Processes MH - Solutions/chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Titanium/*chemistry MH - Waste Disposal, Fluid/methods MH - Water Pollutants, Chemical/*chemistry MH - X-Ray Diffraction EDAT- 2012/03/06 06:00 MHDA- 2012/09/21 06:00 CRDT- 2012/03/06 06:00 PHST- 2011/09/26 00:00 [received] PHST- 2012/01/30 00:00 [revised] PHST- 2012/02/05 00:00 [accepted] PHST- 2012/03/06 06:00 [entrez] PHST- 2012/03/06 06:00 [pubmed] PHST- 2012/09/21 06:00 [medline] AID - S0301-4797(12)00076-X [pii] AID - 10.1016/j.jenvman.2012.02.014 [doi] PST - ppublish SO - J Environ Manage. 2012 Jun 30;101:1-6. doi: 10.1016/j.jenvman.2012.02.014. Epub 2012 Mar 2.