PMID- 22446851 OWN - NLM STAT- MEDLINE DCOM- 20120724 LR - 20131121 IS - 1463-9084 (Electronic) IS - 1463-9076 (Linking) VI - 14 IP - 17 DP - 2012 May 7 TI - Photo-controlled release of zinc metal ions by spiropyran receptors anchored to single-walled carbon nanotubes. PG - 6034-43 LID - 10.1039/c2cp40275k [doi] AB - Light controllable release of antinflammatory zinc ions by a smart multifunctional material composed of spiropyrans and single walled carbon nanotubes (SWNTs) is demonstrated. The exploitation of a number of complementary characterization techniques allows the investigation of both composition and performance of the multifunctional SP/SWNT nanomaterial developed. Moreover, its suitability for potential applications in bio-systems is suggested by the effective removal of the metal catalyst and the introduction of biocompatible linkers into the SP/SWNT material. The realization of potential photo controllable SP/SWNTs based drug delivery systems (DDSs) is envisaged, where nanotubes act as intracellular carriers of light modulated receptors for bioactive agents. FAU - Del Canto, Elisa AU - Del Canto E AD - School of Chemistry/Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), University of Dublin, Trinity College, Dublin 2, Ireland. FAU - Natali, Manuel AU - Natali M FAU - Movia, Dania AU - Movia D FAU - Giordani, Silvia AU - Giordani S LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120323 PL - England TA - Phys Chem Chem Phys JT - Physical chemistry chemical physics : PCCP JID - 100888160 RN - 0 (Benzopyrans) RN - 0 (Drug Carriers) RN - 0 (Indoles) RN - 0 (Ions) RN - 0 (Nanotubes, Carbon) RN - 0 (Nitro Compounds) RN - 0 (spiropyran) RN - J41CSQ7QDS (Zinc) SB - IM MH - Benzopyrans/*chemistry MH - Cell Line, Tumor MH - Drug Carriers/chemistry MH - Humans MH - Indoles/*chemistry MH - Ions/chemistry MH - Light MH - Nanotubes, Carbon/*chemistry MH - Nitro Compounds/*chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Spectrum Analysis, Raman MH - Zinc/*chemistry EDAT- 2012/03/27 06:00 MHDA- 2012/07/25 06:00 CRDT- 2012/03/27 06:00 PHST- 2012/03/27 06:00 [entrez] PHST- 2012/03/27 06:00 [pubmed] PHST- 2012/07/25 06:00 [medline] AID - 10.1039/c2cp40275k [doi] PST - ppublish SO - Phys Chem Chem Phys. 2012 May 7;14(17):6034-43. doi: 10.1039/c2cp40275k. Epub 2012 Mar 23.