PMID- 22503192 OWN - NLM STAT- MEDLINE DCOM- 20120829 LR - 20120504 IS - 1873-2976 (Electronic) IS - 0960-8524 (Linking) VI - 114 DP - 2012 Jun TI - Kinetic modeling of bioregeneration of chlorophenol-loaded granular activated carbon in simultaneous adsorption and biodegradation processes. PG - 179-87 LID - 10.1016/j.biortech.2012.03.065 [doi] AB - A kinetic model incorporating adsorption, desorption and biodegradation processes was developed to describe the bioregeneration of granular activated carbon (GAC) loaded with 4-chlorophenol (4-CP) and 2,4-dichlorophenol (2,4-DCP), respectively, in simultaneous adsorption and biodegradation processes. The model was numerically solved and the results showed that the kinetic model was well-fitted (R(2)>0.83) to the experimental data at different GAC dosages and at various initial 4-CP and 2,4-DCP concentrations. The rate of bioregeneration in simultaneous adsorption and biodegradation processes was influenced by the ratio of initial chlorophenol concentration to GAC dosage. Enhancement in the rate of bioregeneration was achieved by using the lowest ratio under either one of the following experimental conditions: (1) increasing initial chlorophenol concentration at constant GAC dosage and (2) increasing GAC dosage at constant initial chlorophenol concentration. It was found that the rate enhancement was more pronounced under the second experimental condition. CI - Copyright (c) 2012 Elsevier Ltd. All rights reserved. FAU - Oh, Wen-Da AU - Oh WD AD - School of Chemical Sciences, Universiti Sains Malaysia, 11800 Penang, Malaysia. FAU - Lim, Poh-Eng AU - Lim PE FAU - Seng, Chye-Eng AU - Seng CE FAU - Sujari, Amat Ngilmi Ahmad AU - Sujari AN LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120329 PL - England TA - Bioresour Technol JT - Bioresource technology JID - 9889523 RN - 0 (Chlorophenols) RN - 16291-96-6 (Charcoal) SB - IM MH - Adsorption MH - Bacteria, Aerobic/*metabolism MH - Biodegradation, Environmental MH - Charcoal/*chemistry MH - Chlorophenols/*isolation & purification/*metabolism MH - Computer Simulation MH - Kinetics MH - *Models, Biological MH - *Models, Chemical EDAT- 2012/04/17 06:00 MHDA- 2012/08/30 06:00 CRDT- 2012/04/17 06:00 PHST- 2011/12/22 00:00 [received] PHST- 2012/03/12 00:00 [revised] PHST- 2012/03/13 00:00 [accepted] PHST- 2012/04/17 06:00 [entrez] PHST- 2012/04/17 06:00 [pubmed] PHST- 2012/08/30 06:00 [medline] AID - S0960-8524(12)00529-9 [pii] AID - 10.1016/j.biortech.2012.03.065 [doi] PST - ppublish SO - Bioresour Technol. 2012 Jun;114:179-87. doi: 10.1016/j.biortech.2012.03.065. Epub 2012 Mar 29.