PMID- 22512858 OWN - NLM STAT- MEDLINE DCOM- 20120817 LR - 20161125 IS - 1520-5827 (Electronic) IS - 0743-7463 (Linking) VI - 28 IP - 17 DP - 2012 May 1 TI - SPR sensing of bisphenol A using molecularly imprinted nanoparticles immobilized on slab optical waveguide with consecutive parallel Au and Ag deposition bands coexistent with bisphenol A-immobilized Au nanoparticles. PG - 7083-8 LID - 10.1021/la300018t [doi] AB - A slab-type optical waveguide (s_OWG)-based microfluidic SPR measurement system for bisphenol A was developed. This s_OWG possesses consecutive parallel gold and silver deposition bands in the line of plasmon flow, allowing two individual SPR signals to be independently obtained as a result of the difference in resonant reflection spectra of these metals. As a molecular recognition element, molecularly imprinted polymer nanoparticles (MIP-Np) were employed and immobilized on the surface of each of the gold and silver deposition bands. The resonant reflection spectra were measured on the MIP-Np-immobilized consecutive parallel gold and silver deposition bands coexistent with BPA-AuNp. The Ag-based SPR spectra showed a red shift (0.7 nm) when free BPA (0.1 mM) was passed over the BPA-AuNp/immobilized MIP-Np complexes formed on the s_OWG, unlike the case for the Au deposition band, while a large excess of BPA induced a blue shift due to the competitive desorption of BPA-AuNp from the immobilized MIP-Np on the s_OWG. By using the proposed detection system, binding events of other small molecules could be monitored in conjunction with the use of MIP-Np and labeled-AuNp. FAU - Taguchi, Yuki AU - Taguchi Y AD - Graduate School of Engineering, Kobe University, Nada-ku, Kobe, Japan. FAU - Takano, Eri AU - Takano E FAU - Takeuchi, Toshifumi AU - Takeuchi T LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120418 PL - United States TA - Langmuir JT - Langmuir : the ACS journal of surfaces and colloids JID - 9882736 RN - 0 (Aniline Compounds) RN - 0 (Benzhydryl Compounds) RN - 0 (Phenols) RN - 3M4G523W1G (Silver) RN - 7440-57-5 (Gold) RN - GG5LL7OBZC (4,4'-diaminodiphenylmethane) RN - MLT3645I99 (bisphenol A) SB - IM MH - Aniline Compounds/chemistry MH - Benzhydryl Compounds MH - Gold/*chemistry MH - Metal Nanoparticles/*chemistry MH - Molecular Imprinting/*methods MH - *Optical Phenomena MH - Phenols/*analysis/chemistry MH - Silver/*chemistry MH - Surface Plasmon Resonance/*methods EDAT- 2012/04/20 06:00 MHDA- 2012/08/18 06:00 CRDT- 2012/04/20 06:00 PHST- 2012/04/20 06:00 [entrez] PHST- 2012/04/20 06:00 [pubmed] PHST- 2012/08/18 06:00 [medline] AID - 10.1021/la300018t [doi] PST - ppublish SO - Langmuir. 2012 May 1;28(17):7083-8. doi: 10.1021/la300018t. Epub 2012 Apr 18.