PMID- 22520453
OWN - NLM
STAT- MEDLINE
DCOM- 20121026
LR  - 20181201
IS  - 1090-2414 (Electronic)
IS  - 0147-6513 (Linking)
VI  - 80
DP  - 2012 Jun
TI  - Dissipation of pyraclostrobin and its metabolite BF-500-3 in maize under field 
      conditions.
PG  - 252-7
LID - 10.1016/j.ecoenv.2012.03.012 [doi]
AB  - The dissipation and residue of pyraclostrobin and its metabolite BF-500-3 in 
      maize under field conditions were investigated. A sensitive, simple and fast 
      method for simultaneous determination of pyraclostrobin and BF-500-3 in maize 
      matrix was established by high performance liquid chromatography-tandem mass 
      spectrometry (HPLC-MS/MS). The average recoveries of pyraclostrobin and BF-500-3 
      were found in the range of 83.6-104.9% with relative standard deviations (RSDs) 
      of 2.3-10.0%. The results showed that pyraclostrobin dissipated quickly in maize 
      plant with half-lives of 1.6-1.7 days. Its metabolite BF-500-3 showed a tendency 
      of rapid increasing initially and decreasing afterwards. At harvest time, the 
      terminal residues of pyraclostrobin were below the maximum residue limit (MRL) 
      set by USA and Canada in maize grain when measured 7 days after the final 
      application, which suggested that the use of this fungicide was safe for humans. 
      The results could provide guidance to safe and reasonable use of pyraclostrobin 
      in agriculture.
CI  - Copyright (c) 2012 Elsevier Inc. All rights reserved.
FAU - You, Xiangwei
AU  - You X
AD  - College of Science, China Agricultural University, Beijing 100193, PR China.
FAU - Liu, Congyun
AU  - Liu C
FAU - Liu, Fengmao
AU  - Liu F
FAU - Liu, Yanping
AU  - Liu Y
FAU - Dong, Jiannan
AU  - Dong J
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20120419
PL  - Netherlands
TA  - Ecotoxicol Environ Saf
JT  - Ecotoxicology and environmental safety
JID - 7805381
RN  - 0 (Carbamates)
RN  - 0 (Fungicides, Industrial)
RN  - 0 (Pesticide Residues)
RN  - 0 (Pyrazoles)
RN  - 0 (Strobilurins)
RN  - DJW8M9OX1H (pyrachlostrobin)
SB  - IM
MH  - Agriculture
MH  - Canada
MH  - Carbamates/analysis/*metabolism
MH  - China
MH  - Chromatography, High Pressure Liquid
MH  - Environmental Monitoring
MH  - Fungicides, Industrial/analysis/chemistry/*metabolism
MH  - Half-Life
MH  - Pesticide Residues/analysis/chemistry/*metabolism
MH  - Pyrazoles/analysis/*metabolism
MH  - Strobilurins
MH  - Tandem Mass Spectrometry
MH  - United States
MH  - Zea mays/chemistry/*metabolism
EDAT- 2012/04/24 06:00
MHDA- 2012/10/27 06:00
CRDT- 2012/04/24 06:00
PHST- 2011/12/03 00:00 [received]
PHST- 2012/03/09 00:00 [revised]
PHST- 2012/03/14 00:00 [accepted]
PHST- 2012/04/24 06:00 [entrez]
PHST- 2012/04/24 06:00 [pubmed]
PHST- 2012/10/27 06:00 [medline]
AID - S0147-6513(12)00099-1 [pii]
AID - 10.1016/j.ecoenv.2012.03.012 [doi]
PST - ppublish
SO  - Ecotoxicol Environ Saf. 2012 Jun;80:252-7. doi: 10.1016/j.ecoenv.2012.03.012. 
      Epub 2012 Apr 19.