PMID- 22542082 OWN - NLM STAT- MEDLINE DCOM- 20120927 LR - 20161125 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 88 IP - 7 DP - 2012 Aug TI - Combined approaches to determine the impact of wood fire on PCDD/F and PCB contamination of the environment: a case study. PG - 806-12 LID - 10.1016/j.chemosphere.2012.03.086 [doi] AB - Fires might be the source of persistent organic pollutants (POPs) such as dioxins, furans (PCDD/Fs) and/or polychlorobiphenyls (PCBs) in the environment. In the perspective of defining legal responsibilities a thorough characterization of the impact of such an event should be carried out. However, such characterization is not easy as the environment integrates both local and diffuse sources of such molecules. Thus, a combined approach, which includes gathering field surveys, modeling and laboratory experiments, should be conducted. The objective of this work is to illustrate different approaches to give sufficient insight to determine the actual impact of wood fire on the environment. The work was carried out at the vicinity of a burnt down parcel. The fired material was a mixture of wood and PCB-contaminated soils as the site was a former pyralene-disposal site. Modeling, soil and lichen sampling and experimental combustion were carried out to delineate the contamination for each chemical and to define the area within the fire that was responsible for the environmental contamination. Concentrations of PCDD/F and PCBs were very high on the burnt plot. The combined approach determined that the furans were the predominant compounds in the smoke emitted by the fire. Based on this tracer, it was possible to demonstrate that in terms of environmental contamination of PCDD/F, the impact of the fire was restricted to a 2km radius from the burnt down plot. For PCBs, no specific tracer was identified. In this case, the delineation of the impact could only be empirical, based on the total concentration of the chemicals. CI - Copyright (c) 2012 Elsevier Ltd. All rights reserved. FAU - Denys, Sebastien AU - Denys S AD - INERIS, Parc Technologique ALATA, BP 2, F-60550 Verneuil en Halatte, France. sebastien.denys@anses.fr FAU - Gombert, Dominique AU - Gombert D FAU - Tack, Karine AU - Tack K LA - eng PT - Journal Article DEP - 20120426 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Environmental Pollutants) RN - 0 (Polychlorinated Dibenzodioxins) RN - 0 (Soil Pollutants) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Environmental Monitoring MH - Environmental Pollutants/*analysis MH - Geography MH - Polychlorinated Biphenyls/*analysis MH - Polychlorinated Dibenzodioxins/*analogs & derivatives/analysis MH - Soil Pollutants/analysis MH - *Wood EDAT- 2012/05/01 06:00 MHDA- 2012/09/28 06:00 CRDT- 2012/05/01 06:00 PHST- 2011/01/19 00:00 [received] PHST- 2012/03/24 00:00 [revised] PHST- 2012/03/31 00:00 [accepted] PHST- 2012/05/01 06:00 [entrez] PHST- 2012/05/01 06:00 [pubmed] PHST- 2012/09/28 06:00 [medline] AID - S0045-6535(12)00466-3 [pii] AID - 10.1016/j.chemosphere.2012.03.086 [doi] PST - ppublish SO - Chemosphere. 2012 Aug;88(7):806-12. doi: 10.1016/j.chemosphere.2012.03.086. Epub 2012 Apr 26.