PMID- 22579403 OWN - NLM STAT- MEDLINE DCOM- 20120813 LR - 20131121 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 221-222 DP - 2012 Jun 30 TI - Emissions from open burning of used agricultural pesticide containers. PG - 236-41 LID - 10.1016/j.jhazmat.2012.04.041 [doi] AB - Emissions from simulated open burning of used agricultural pesticide containers were sampled for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs/PCDFs), polycyclic aromatic hydrocarbon compounds (PAHs), and particle matter (PM(10) and PM(2.5)). Clean high density polyethylene (HDPE) containers, containers with trace pesticide, and triple-rinsed containers were burned separately in an open combustion facility and their emissions compared. Two common chlorinated pesticides were used: 2,4-dichlorophenoxyacetic acid (2,4-D) and 1-chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine (atrazine). PCDD/PCDF emission factors ranged from 0.1 to 24ng toxic equivalents (TEQ)/kg C burned with a mean and median of 4.9 and 1.9ng TEQ/kgC burned, respectively. In a limited number of trials, the trace 2,4-D in the HDPE container led to a statistically significant increase in PCDD/PCDF formation compare to all other conditions. Residual atrazine did not lead to more PCDD/PCDF than the unrinsed 2,4-D container. Total (16 compounds) PAH emission factors varied from 1.5 to 6.7mg/kgC burned. These limited data suggest that rinsing the 2,4-D container prior to burning reduces both PCDD/PCDF and PAH emissions. Nine PM(2.5) emission factors ranged from 9 to 35mg/gC burned and ten PM(10) values ranged from 6 to 43mg/gC burned. Neither pesticide appeared to have any effect on PM concentration. CI - Published by Elsevier B.V. FAU - Gullett, Brian K AU - Gullett BK AD - U.S. Environmental Protection Agency, Office of Research and Development, Research Triangle Park, NC 27711, USA. Gullett.Brian@epamail.epa.gov FAU - Tabor, Dennis AU - Tabor D FAU - Touati, Abderrahmane AU - Touati A FAU - Kasai, Jeanne AU - Kasai J FAU - Fitz, Nancy AU - Fitz N LA - eng PT - Journal Article PT - Research Support, U.S. Gov't, Non-P.H.S. DEP - 20120421 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Air Pollutants) RN - 0 (Herbicides) RN - 0 (Pesticides) RN - 0 (Polycyclic Compounds) RN - QJA9M5H4IM (Atrazine) SB - IM MH - *Agriculture MH - Air Pollutants/*analysis MH - Atrazine/analysis MH - Herbicides/analysis MH - *Hot Temperature MH - Particle Size MH - *Pesticides MH - Polycyclic Compounds/analysis EDAT- 2012/05/15 06:00 MHDA- 2012/08/14 06:00 CRDT- 2012/05/15 06:00 PHST- 2012/02/06 00:00 [received] PHST- 2012/04/13 00:00 [revised] PHST- 2012/04/16 00:00 [accepted] PHST- 2012/05/15 06:00 [entrez] PHST- 2012/05/15 06:00 [pubmed] PHST- 2012/08/14 06:00 [medline] AID - S0304-3894(12)00432-3 [pii] AID - 10.1016/j.jhazmat.2012.04.041 [doi] PST - ppublish SO - J Hazard Mater. 2012 Jun 30;221-222:236-41. doi: 10.1016/j.jhazmat.2012.04.041. Epub 2012 Apr 21.