PMID- 22580747 OWN - NLM STAT- MEDLINE DCOM- 20130301 LR - 20211021 IS - 1573-2959 (Electronic) IS - 0167-6369 (Linking) VI - 185 IP - 2 DP - 2013 Feb TI - Screening for Stockholm Convention persistent organic pollutants in the Bosna River (Bosnia and Herzogovina). PG - 1671-83 LID - 10.1007/s10661-012-2659-0 [doi] AB - The Stockholm Convention, which aspires to manage persistent organic pollutants (POPs) at the international level, was recently ratified in Bosnia and Herzegovina (BiH). Despite this fact, there is in general a paucity of data regarding the levels of POPs in the environment in BiH. In the present study, screening for POPs was conducted in one of the country's major rivers, the Bosna. A two-pronged approach was applied using passive samplers to detect the freely dissolved and bioavailable concentrations in the water phase and sediment analysis to provide an integrated measure of historical contamination. At several places along the river, the concentrations of polycyclic aromatic hydrocarbons (PAH) were high and exhibited potential for both chronic and acute effects to biota. River water also showed elevated concentrations of PAH, up to 480 ng L(-1) near the city of Doboj, and diagnostic ratios suggested combustion sources for the contamination present in both types of sample. The levels of the other contaminants measured-polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and polybrominated diphenyl ethers--were generally low in the water phase. However, PCBs and some OCPs were present in river sediments at levels which breach the international criteria and thus suggest potential for ecological damage. Additionally, the levels of heptachlor breached these criteria in many of the sites investigated. This study presents the first screening data for some of these Stockholm Convention relevant compounds in BiH and reveals both low concentrations of some chemical groups, but significant point sources and historic contamination for others. FAU - Harman, Christopher AU - Harman C AD - Norwegian Institute for Water Research, NIVA, Oslo Centre for Interdisciplinary Environmental and Social Research, CIENS, Gaustadalleen 21, 0349 Oslo, Norway. CHA@niva.no FAU - Grung, Merete AU - Grung M FAU - Djedjibegovic, Jasmina AU - Djedjibegovic J FAU - Marjanovic, Aleksandra AU - Marjanovic A FAU - Sober, Miroslav AU - Sober M FAU - Sinanovic, Kemo AU - Sinanovic K FAU - Fjeld, Eirik AU - Fjeld E FAU - Rognerud, Sigurd AU - Rognerud S FAU - Ranneklev, Sissel Brit AU - Ranneklev SB FAU - Larssen, Thorjorn AU - Larssen T LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120513 PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Organic Chemicals) RN - 0 (Pesticides) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - 0 (Water Pollutants, Chemical) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Bosnia and Herzegovina MH - Environmental Monitoring/legislation & jurisprudence/*methods MH - Environmental Policy MH - Halogenated Diphenyl Ethers MH - Hydrocarbons, Chlorinated/analysis MH - Organic Chemicals/analysis MH - Pesticides/analysis MH - Polychlorinated Biphenyls/analysis MH - Polycyclic Aromatic Hydrocarbons/analysis MH - Rivers/*chemistry MH - Sweden MH - Water Pollutants, Chemical/*analysis MH - Water Pollution, Chemical/legislation & jurisprudence/statistics & numerical data EDAT- 2012/05/15 06:00 MHDA- 2013/03/02 06:00 CRDT- 2012/05/15 06:00 PHST- 2011/09/21 00:00 [received] PHST- 2012/04/23 00:00 [accepted] PHST- 2012/05/15 06:00 [entrez] PHST- 2012/05/15 06:00 [pubmed] PHST- 2013/03/02 06:00 [medline] AID - 10.1007/s10661-012-2659-0 [doi] PST - ppublish SO - Environ Monit Assess. 2013 Feb;185(2):1671-83. doi: 10.1007/s10661-012-2659-0. Epub 2012 May 13.