PMID- 22608416
OWN - NLM
STAT- MEDLINE
DCOM- 20120913
LR  - 20131121
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 94
DP  - 2012 May 30
TI  - Solidified floating organic drop microextraction combined with ETV-ICP-MS for the 
      determination of trace heavy metals in environmental water samples.
PG  - 70-6
LID - 10.1016/j.talanta.2012.02.053 [doi]
AB  - A new method of solidified floating organic drop microextraction (SFODME) 
      combined with electrothermal vaporization (ETV)-inductively coupled plasma mass 
      spectrometry (ICP-MS) was developed for the determination of trace heavy metals 
      in environmental water samples with sodium diethyldithiocarbamate (DDTC) as both 
      chelating reagent in SFODME and chemical modifier in ETV. The factors affecting 
      the microextraction efficiency were studied in detail and the optimal extraction 
      conditions were established. Under the optimal conditions, the limits of 
      detection (LODs) for SFODME-ETV-ICP-MS determination of Co, Pd, Cd, Hg, Pb and Bi 
      were found to be 0.0060, 0.0091, 0.0020, 0.0041, 0.0170 and 0.0041 ng mL(-1), 
      respectively, with the relative standard deviations (RSDs) of 2.8-10.0% (c=0.5 ng 
      mL(-1), n=7). The developed method was successfully applied to the analysis of 
      six target metals in Yangtze River and East Lake water samples with recoveries 
      ranging from 77.7 to 119.1%. To validate the accuracy of the method, a certified 
      reference material of Environmental Water (GSBZ50009-88) was analyzed and the 
      determined values were in good agreement with the certified values.
CI  - Copyright (c) 2012 Elsevier B.V. All rights reserved.
FAU - Guo, Xueqin
AU  - Guo X
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan 430072, PR China.
FAU - He, Man
AU  - He M
FAU - Chen, Beibei
AU  - Chen B
FAU - Hu, Bin
AU  - Hu B
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20120301
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Chelating Agents)
RN  - 0 (Metals, Heavy)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
RN  - 99Z2744345 (Ditiocarb)
SB  - IM
MH  - Chelating Agents/chemistry
MH  - Ditiocarb/chemistry
MH  - Environmental Monitoring
MH  - Hot Temperature
MH  - Lakes/*chemistry
MH  - Limit of Detection
MH  - Metals, Heavy/*analysis
MH  - Reference Standards
MH  - Solid Phase Microextraction/*methods
MH  - Spectrophotometry, Atomic
MH  - Volatilization
MH  - Water/*chemistry
MH  - Water Pollutants, Chemical/*analysis
EDAT- 2012/05/23 06:00
MHDA- 2012/09/14 06:00
CRDT- 2012/05/22 06:00
PHST- 2011/12/12 00:00 [received]
PHST- 2012/02/21 00:00 [revised]
PHST- 2012/02/22 00:00 [accepted]
PHST- 2012/05/22 06:00 [entrez]
PHST- 2012/05/23 06:00 [pubmed]
PHST- 2012/09/14 06:00 [medline]
AID - S0039-9140(12)00191-9 [pii]
AID - 10.1016/j.talanta.2012.02.053 [doi]
PST - ppublish
SO  - Talanta. 2012 May 30;94:70-6. doi: 10.1016/j.talanta.2012.02.053. Epub 2012 Mar 
      1.