PMID- 22609680 OWN - NLM STAT- MEDLINE DCOM- 20121206 LR - 20181201 IS - 1873-6750 (Electronic) IS - 0160-4120 (Linking) VI - 45 DP - 2012 Sep 15 TI - Halogenated flame retardants in home-produced eggs from an electronic waste recycling region in South China: levels, composition profiles, and human dietary exposure assessment. PG - 122-8 LID - 10.1016/j.envint.2012.04.006 [doi] AB - Three regulated halogenated flame retardants (HFRs), i.e., polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs) and hexabromocyclododecanes (HBCDs), and several alternative HFRs (AHFRs) including Dechlorane Plus (DP), decabromodiphenyl ethane (DBDPE), and 1,2-bis(2,4,6-tribromophenoxy) ethane (BTBPE), were investigated in the home-produced eggs from three recycling sites and a reference site in an electronic waste (e-waste) recycling region, South China. Mean levels of HFRs in eggs from the recycling sites ranged 2640-14100, 700-1620, 44-350, and 720-3920 ng/g lipid weight for summation operatorPBDEs, summation operatorPBBs, summation operatorHBCDs, and summation operatorAHFRs, respectively, which were one to two orders of magnitude higher than those examined in the reference site. PBDEs were the predominant HFR in those eggs, with contributions >50% to the total HFRs; followed by PBBs and the AHFRs (contributing 14-22% in average). The alpha-HBCD was the predominant diastereoisomers of HBCDs, with preferential enrichment of the (-)-enantiomer in most of the eggs; but no significant stereoselective enrichment of the DP isomers was observed in these eggs. The average estimated daily intakes (EDIs) of PBDEs, PBBs, HBCDs, and the AHFRs via eggs from the recycling sites ranged 4200-20000, 1120-2440, 80-490, and 970-4530 ng/day, respectively, which were one to two orders of magnitude higher than those reported from other parts of the world. The potential adverse effects of these HFRs to human health in the e-waste sites should be further investigated. This is the first report on the isomer compositions of DP and the chiral signatures of HBCDs in hen eggs. CI - Copyright (c) 2012 Elsevier Ltd. All rights reserved. FAU - Zheng, Xiao-Bo AU - Zheng XB AD - State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China. FAU - Wu, Jiang-Ping AU - Wu JP FAU - Luo, Xiao-Jun AU - Luo XJ FAU - Zeng, Yan-Hong AU - Zeng YH FAU - She, Ya-Zhe AU - She YZ FAU - Mai, Bi-Xian AU - Mai BX LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120518 PL - Netherlands TA - Environ Int JT - Environment international JID - 7807270 RN - 0 (Bromobenzenes) RN - 0 (Environmental Pollutants) RN - 0 (Flame Retardants) RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Hydrocarbons, Brominated) RN - 0 (Polybrominated Biphenyls) RN - 0 (decabromodiphenyl ethane) RN - 5I9835JO3M (hexabromocyclododecane) SB - IM MH - Animals MH - Bromobenzenes/analysis/metabolism MH - Chickens MH - China MH - Diet/*statistics & numerical data MH - Eggs/*analysis/statistics & numerical data MH - *Electronic Waste MH - Environmental Exposure/*statistics & numerical data MH - Environmental Pollutants/analysis/*metabolism MH - Environmental Pollution/statistics & numerical data MH - Flame Retardants/analysis/*metabolism MH - Halogenated Diphenyl Ethers/analysis/metabolism MH - Humans MH - Hydrocarbons, Brominated/analysis/metabolism MH - Polybrominated Biphenyls/analysis/metabolism EDAT- 2012/05/23 06:00 MHDA- 2012/12/10 06:00 CRDT- 2012/05/22 06:00 PHST- 2012/03/13 00:00 [received] PHST- 2012/04/11 00:00 [revised] PHST- 2012/04/11 00:00 [accepted] PHST- 2012/05/22 06:00 [entrez] PHST- 2012/05/23 06:00 [pubmed] PHST- 2012/12/10 06:00 [medline] AID - S0160-4120(12)00078-5 [pii] AID - 10.1016/j.envint.2012.04.006 [doi] PST - ppublish SO - Environ Int. 2012 Sep 15;45:122-8. doi: 10.1016/j.envint.2012.04.006. Epub 2012 May 18.