PMID- 22655361
OWN - NLM
STAT- MEDLINE
DCOM- 20120628
LR  - 20190911
IS  - 1001-0742 (Print)
IS  - 1001-0742 (Linking)
VI  - 24
IP  - 3
DP  - 2012
TI  - Glucose production from hydrolysis of cellulose over a novel silica catalyst 
      under hydrothermal conditions.
PG  - 473-8
AB  - A novel silica catalyst was synthesized by evaporation-induced self-assembly 
      (EISA) method and tested for the catalytic selective hydrolysis of cellulose to 
      glucose. This silica catalyst exhibited a higher catalytic activity than other 
      oxides prepared by the same method, such as ZrO2, TiO2, and Al2O3. Using silica 
      as a catalyst, cellulose was selectively hydrolyzed into glucose with a glucose 
      yield as high as 50% under hydrothermal conditions without hydrogen gas. The 
      silica catalyst was characterized by Brunauer-Emmett-Teller (BET), X-ray 
      diffraction (XRD) and transmission electron microscopy (TEM). The results of 
      temperature-programmed desorption of ammonia (NH3-TPD) and textural properties 
      indicated that the synergistic effect between strong acidity and a suitable pore 
      diameter of the silica catalyst may be responsible for its high activity. In 
      addition, the catalyst was recyclable and showed excellent stability during the 
      recycle catalytic runs.
FAU - Wang, Huayu
AU  - Wang H
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Zhang, Changbin
AU  - Zhang C
FAU - He, Hong
AU  - He H
FAU - Wang, Lian
AU  - Wang L
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Netherlands
TA  - J Environ Sci (China)
JT  - Journal of environmental sciences (China)
JID - 100967627
RN  - 7631-86-9 (Silicon Dioxide)
RN  - 9004-34-6 (Cellulose)
RN  - IY9XDZ35W2 (Glucose)
SB  - IM
MH  - Carbohydrate Conformation
MH  - Catalysis
MH  - Cellulose/*chemistry
MH  - Glucose/*chemistry
MH  - Hot Temperature
MH  - Hydrolysis
MH  - Microscopy, Electron, Transmission
MH  - Silicon Dioxide/*chemistry
EDAT- 2012/06/05 06:00
MHDA- 2012/06/29 06:00
CRDT- 2012/06/05 06:00
PHST- 2012/06/05 06:00 [entrez]
PHST- 2012/06/05 06:00 [pubmed]
PHST- 2012/06/29 06:00 [medline]
AID - 10.1016/s1001-0742(11)60795-x [doi]
PST - ppublish
SO  - J Environ Sci (China). 2012;24(3):473-8. doi: 10.1016/s1001-0742(11)60795-x.