PMID- 22679826
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20130712
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 30
IP  - 2
DP  - 2012 Feb
TI  - [Determination of five synthetic musks in perfume by headspace solid-phase 
      microextraction and gas chromatography-mass spectrometry].
PG  - 135-40
AB  - A method for headspace solid-phase microextraction (HS-SPME), followed by gas 
      chromatography-mass spectrometry (GC-MS) analysis was established for the 
      determination of five commonly used synthetic musks in perfume. Two polycyclic 
      musks (celestolide and tonalide) and three nitro musks (musk ambrette, musk 
      xylene and musk ketone) were used as analytes in the optimization of the 
      analytical method. Six parameters, such as the extraction temperature, 
      equilibrium time, extraction time, desorption time, injector temperature and 
      solution of salting out, were optimized by exposing the 65 microm 
      polydimethylsiloxane-divinyl-benzene (PDMS-DVB) fiber to the headspace of 
      magnetically stirred (600 r/min) sample. According to the results of the 
      optimization experiments, the following conclusion can be drawn: The 
      water-diluted sample in a 10 mL headspace-vial was efficiently extracted for 20 
      min after the system was equilibrated for 3 min at 60 degrees C. After 
      extraction, the fiber was immediately inserted into the GC injector and desorbed 
      at 250 degrees C for 3 min. The spiked recoveries were in the range of 82.0% - 
      103.3% and the relative standard deviations (RSDs) were between 1.8% and 9.4%. 
      Meanwhile, the limits of detection (LODs) ranged from 0.6 ng/g to 2.1 ng/g. This 
      method is characterized by rapidity, high sensitivity, good linearity and 
      repeatability for all the target compounds. It is applicable to the analysis of 
      synthetic musks in perfumes.
FAU - Wang, Guannan
AU  - Wang G
AD  - College of Science, Beijing University of Chemical Technology, Beijing 100029, 
      China.
FAU - Tang, Hua
AU  - Tang H
FAU - Chen, Dazhou
AU  - Chen D
FAU - Feng, Jie
AU  - Feng J
FAU - Li, Lei
AU  - Li L
LA  - chi
PT  - English Abstract
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
EDAT- 2012/06/12 06:00
MHDA- 2012/06/12 06:01
CRDT- 2012/06/12 06:00
PHST- 2012/06/12 06:00 [entrez]
PHST- 2012/06/12 06:00 [pubmed]
PHST- 2012/06/12 06:01 [medline]
AID - 10.3724/sp.j.1123.2011.10018 [doi]
PST - ppublish
SO  - Se Pu. 2012 Feb;30(2):135-40. doi: 10.3724/sp.j.1123.2011.10018.