PMID- 22686136
OWN - NLM
STAT- MEDLINE
DCOM- 20121031
LR  - 20131121
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 28
IP  - 25
DP  - 2012 Jun 26
TI  - Formation of self-aggregated structures of different types in water of chiral 
      polymerizable amphiphiles from L-tyrosine and L-phenylalanine.
PG  - 9378-86
LID - 10.1021/la3015095 [doi]
AB  - Sodium salts of maleamic acid derivatives from lauryl esters of L-tyrosine (MTNa) 
      and L-phenylalanine (MPNa) were synthesized and characterized. The aggregated 
      structures of MTNa and MPNa in water were investigated, employing several 
      independent methods. MPNa showed secondary aggregated structures in contrast to 
      MTNa at concentrations of >1 x 10(-3) M. The results from dynamic light 
      scattering, transmittance, conductivity, and viscosity measurements suggested the 
      formation of aggregated structures of different types in MTNa and MPNa solutions. 
      The measured fluorescence anisotropy (r) at 0.180 of the fluoroprobe, 
      1,6-diphenyl-1,3,5-hexatriene (DPH), and the d spacing of 38 A from small-angle 
      X-ray diffraction (SAXD) experiments confirmed the bilayer structures in MPNa. 
      Scanning electron microscope (SEM) images provided the morphological features. 
      The emulsion produced using MPNa solution was more stable. The confocal 
      fluorescence microscopy image of the emulsion from MPNa confirmed the entrapment 
      of water-soluble dye, rhodamine. The models of MTNa and MPNa molecules and the 
      aggregated structures are presented.
FAU - Angayarkanny, S
AU  - Angayarkanny S
AD  - Industrial Chemistry Laboratory, Council of Scientific and Industrial Research 
      (CSIR), Adyar, Chennai 600 020, India.
FAU - Vijay, R
AU  - Vijay R
FAU - Baskar, Geetha
AU  - Baskar G
FAU - Mandal, A B
AU  - Mandal AB
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20120611
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
RN  - 0 (Emulsions)
RN  - 0 (Esters)
RN  - 0 (Maleates)
RN  - 0 (Pyrenes)
RN  - 059QF0KO0R (Water)
RN  - 1720-32-7 (Diphenylhexatriene)
RN  - 42HK56048U (Tyrosine)
RN  - 47E5O17Y3R (Phenylalanine)
RN  - 9E0T7WFW93 (pyrene)
RN  - MJS1DTX3X1 (maleamic acid)
SB  - IM
MH  - Diphenylhexatriene/chemistry
MH  - Emulsions
MH  - Esters
MH  - *Hydrophobic and Hydrophilic Interactions
MH  - Maleates/chemistry
MH  - Models, Molecular
MH  - Molecular Conformation
MH  - Phenylalanine/*chemistry
MH  - *Polymerization
MH  - Pyrenes/chemistry
MH  - Spectrometry, Fluorescence
MH  - Stereoisomerism
MH  - Surface Tension
MH  - Tyrosine/*chemistry
MH  - Viscosity
MH  - Water/*chemistry
EDAT- 2012/06/13 06:00
MHDA- 2012/11/01 06:00
CRDT- 2012/06/13 06:00
PHST- 2012/06/13 06:00 [entrez]
PHST- 2012/06/13 06:00 [pubmed]
PHST- 2012/11/01 06:00 [medline]
AID - 10.1021/la3015095 [doi]
PST - ppublish
SO  - Langmuir. 2012 Jun 26;28(25):9378-86. doi: 10.1021/la3015095. Epub 2012 Jun 11.