PMID- 22777965
OWN - NLM
STAT- MEDLINE
DCOM- 20130102
LR  - 20120813
IS  - 1521-3927 (Electronic)
IS  - 1022-1336 (Linking)
VI  - 33
IP  - 16
DP  - 2012 Aug 28
TI  - Rare Earth metal-mediated group transfer polymerization of vinylphosphonates.
PG  - 1327-45
LID - 10.1002/marc.201200278 [doi]
AB  - Recent studies have shown that poly(vinylphosphonate)s are readily accessible by 
      rare earth metal-mediated group transfer polymerization (GTP). This article 
      highlights the progress in this new field and advantages of GTP in comparison to 
      classical anionic and radical polymerization approaches. Late lanthanide 
      metallocenes proved to be efficient initiators and highly active catalysts for 
      vinylphosphonate polymerization yielding polymers of precise molecular weight and 
      low polydispersity. Using this method, our group has developed a 
      surface-initiated GTP to prepare poly(vinylphosphonate) brushes. In combination 
      with different ester cleavage strategies, rare earth metal-mediated GTP is an 
      efficient way to create well-defined high-molecular-weight poly(vinylphosphonic 
      acid).
CI  - Copyright (c) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Salzinger, Stephan
AU  - Salzinger S
AD  - WACKER-Lehrstuhl fur Makromolekulare Chemie, Technische Universitat Munchen, 
      Garching, Germany.
FAU - Rieger, Bernhard
AU  - Rieger B
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PT  - Review
DEP - 20120710
PL  - Germany
TA  - Macromol Rapid Commun
JT  - Macromolecular rapid communications
JID - 9888239
RN  - 0 (Metals, Rare Earth)
RN  - 0 (Organophosphonates)
RN  - 0 (Polymers)
RN  - 0 (Vinyl Compounds)
RN  - 1746-03-8 (vinylphosphonic acid)
SB  - IM
MH  - Kinetics
MH  - Metals, Rare Earth/*chemistry
MH  - Molecular Weight
MH  - Organophosphonates/chemistry
MH  - Polymerization
MH  - Polymers/chemical synthesis/*chemistry
MH  - Vinyl Compounds/chemistry
EDAT- 2012/07/11 06:00
MHDA- 2013/01/03 06:00
CRDT- 2012/07/11 06:00
PHST- 2012/04/20 00:00 [received]
PHST- 2012/07/11 06:00 [entrez]
PHST- 2012/07/11 06:00 [pubmed]
PHST- 2013/01/03 06:00 [medline]
AID - 10.1002/marc.201200278 [doi]
PST - ppublish
SO  - Macromol Rapid Commun. 2012 Aug 28;33(16):1327-45. doi: 10.1002/marc.201200278. 
      Epub 2012 Jul 10.