PMID- 22799188 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20140702 LR - 20190923 IS - 1000-8713 (Print) IS - 1000-8713 (Linking) VI - 30 IP - 4 DP - 2012 Apr TI - [Determination of trace aromatic amines in waste water using microextraction combined with ion chromatography]. PG - 345-9 AB - The aim of this work is to develop a simple, selective, sensitive and inexpensive analytical method for the simultaneous determination of several aromatic amines. In this work, a new method for the determination of trace aromatic amines, including o-toluidine and 4-chloroaniline in waste water was developed by hollow fiber membrane extraction with ion chromatography. The optimal extraction conditions were as follows: by using 1-octanol as the organic phase with 500 g/L NaCl and 0.01 mol/L NaOH as the donor phase, and 0.1 mol/L HCl as the acceptor phase, the extraction was performed at a stirring rate of 430 r/min for 30 min. The linear range of both of o-toluidine and 4-chloroaniline was 0.005 - 0.1 mg/L, with correlation coefficients larger than 0. 999. The detection limits of o-toluidine and 4-chloroaniline were 0.2 microg/L and 0.5 microg/L with the relative standard deviations (RSDs) of 0.85% and 3.38%, respectively. The method has been applied to the simultaneous determination of trace aromatic amines including o-toluidine and 4-chloroaniline in the waste water. FAU - Zhu, Yin AU - Zhu Y AD - College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzho 310014, China. FAU - Zhu, Yan AU - Zhu Y FAU - Wang, Lili AU - Wang L LA - chi PT - English Abstract PT - Journal Article PL - China TA - Se Pu JT - Se pu = Chinese journal of chromatography JID - 9424804 EDAT- 2012/07/18 06:00 MHDA- 2012/07/18 06:01 CRDT- 2012/07/18 06:00 PHST- 2012/07/18 06:00 [entrez] PHST- 2012/07/18 06:00 [pubmed] PHST- 2012/07/18 06:01 [medline] AID - 10.3724/sp.j.1123.2011.12075 [doi] PST - ppublish SO - Se Pu. 2012 Apr;30(4):345-9. doi: 10.3724/sp.j.1123.2011.12075.