PMID- 22863578 OWN - NLM STAT- MEDLINE DCOM- 20130114 LR - 20221207 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 235-236 DP - 2012 Oct 15 TI - Removal of phenol from synthetic waste water using Gemini micellar-enhanced ultrafiltration (GMEUF). PG - 128-37 LID - 10.1016/j.jhazmat.2012.07.031 [doi] AB - Comprehensive studies were conducted on the phenol wastewater ultrafiltration (UF) with the help of various concentrations of cationic Gemini surfactant (N1-dodecyl-N1,N1,N2,N2-tetramethyl-N2-octylethane-1,2-diaminium bromide, CG), conventional cationic surfactant (dodecyl trimethyl ammonium bromide, DTAB), anionic surfactant (sodium dodecyl sulfate, SDS) and nonionic surfactant ((dodecyloxy)polyethoxyethanol, Brij35). A flat sheet module with polyethersulfone (PES) membrane was employed in this investigation. The effects of feed concentration (phenol and surfactant) on the retention of phenol and surfactant, permeate flux and membrane fouling by micelles were evaluated. The distribution coefficient (D), the loading of the micelles (L(m)) and the equilibrium distribution constant (K) were also utilized to estimate the micellar-enhanced ultrafiltration ability for phenol. Scanning electron microscope (SEM), Fourier transform infrared spectrometer with attenuated total reflectance accessory (ATR-FTIR) and mercury porosimeter were applied to analyze membrane surface morphology, membrane material characteristics and membrane fouling for the original and fouled membranes. Based on the above analysis, the performance of the selected Gemini surfactant was proved superior in the following aspects: retention of phenol/surfactant (peak value is 95.8% for phenol retention), permeate flux and membrane fouling with respect to other conventional surfactants possessing equal alkyl chain length. These results demonstrated that CG surfactant with exceptional structure has favorable prospects in the treatment of phenol wastewater by the micellar-enhanced ultrafiltration. CI - Copyright (c) 2012 Elsevier B.V. All rights reserved. FAU - Zhang, Wenxiang AU - Zhang W AD - MOE Key Laboratory of Regional Energy and Environmental Systems Optimization, Resources and Environmental Research Academy, North China Electric Power University, Beijing 102206, China. FAU - Huang, Guohe AU - Huang G FAU - Wei, Jia AU - Wei J FAU - Li, Huiqin AU - Li H FAU - Zheng, Rubing AU - Zheng R FAU - Zhou, Ya AU - Zhou Y LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120720 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Micelles) RN - 0 (Surface-Active Agents) RN - 0 (Waste Water) RN - 0 (Water Pollutants, Chemical) RN - 339NCG44TV (Phenol) SB - IM MH - Micelles MH - Phenol/chemistry/*isolation & purification MH - Surface-Active Agents/*chemistry MH - Ultrafiltration/methods MH - Waste Disposal, Fluid/*methods MH - Wastewater MH - Water Pollutants, Chemical/chemistry/*isolation & purification MH - Water Purification/methods EDAT- 2012/08/07 06:00 MHDA- 2013/01/15 06:00 CRDT- 2012/08/07 06:00 PHST- 2012/04/27 00:00 [received] PHST- 2012/07/12 00:00 [revised] PHST- 2012/07/14 00:00 [accepted] PHST- 2012/08/07 06:00 [entrez] PHST- 2012/08/07 06:00 [pubmed] PHST- 2013/01/15 06:00 [medline] AID - S0304-3894(12)00761-3 [pii] AID - 10.1016/j.jhazmat.2012.07.031 [doi] PST - ppublish SO - J Hazard Mater. 2012 Oct 15;235-236:128-37. doi: 10.1016/j.jhazmat.2012.07.031. Epub 2012 Jul 20.