PMID- 22890151 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20130107 LR - 20120830 IS - 1463-9084 (Electronic) IS - 1463-9076 (Linking) VI - 14 IP - 37 DP - 2012 Oct 5 TI - Layer-by-layer inkjet printing of fabricating reduced graphene-polyoxometalate composite film for chemical sensors. PG - 12757-63 LID - 10.1039/c2cp41561e [doi] AB - Graphene oxide (GO) nanosheets and polyoxometalate such as H(3)PW(12)O(40) (PTA) are prepared into a multilayer film via a layer-by-layer inkjet printing method. The GO/PTA composite thin film shows linear, uniform and regular layer-by-layer growth. Under UV-irradiation, a photoreduction reaction takes place in the film which converts GO to reduced GO (rGO) due to the photoreduction activity of polyoxometalate clusters. According to the cyclic voltammograms measurement, the rGO/PTA composite film displays good electrocatalytic activity for the oxidation of dopamine (DA). The oxidation peak current (I(pa)) increases gradually with increasing the dopamine concentration, which may be used in electrochemical biosensors. FAU - Zhang, Hui AU - Zhang H AD - Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, PR China. zhhui@ahu.edu.cn FAU - Xie, Anjian AU - Xie A FAU - Shen, Yuhua AU - Shen Y FAU - Qiu, Lingguang AU - Qiu L FAU - Tian, Xingyou AU - Tian X LA - eng PT - Journal Article DEP - 20120813 PL - England TA - Phys Chem Chem Phys JT - Physical chemistry chemical physics : PCCP JID - 100888160 EDAT- 2012/08/15 06:00 MHDA- 2012/08/15 06:01 CRDT- 2012/08/15 06:00 PHST- 2012/08/15 06:00 [entrez] PHST- 2012/08/15 06:00 [pubmed] PHST- 2012/08/15 06:01 [medline] AID - 10.1039/c2cp41561e [doi] PST - ppublish SO - Phys Chem Chem Phys. 2012 Oct 5;14(37):12757-63. doi: 10.1039/c2cp41561e. Epub 2012 Aug 13.