PMID- 22895739 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20130314 LR - 20160512 IS - 1618-2650 (Electronic) IS - 1618-2642 (Linking) VI - 404 IP - 10 DP - 2012 Dec TI - LED-LED portable oxygen gas sensor. PG - 2851-8 LID - 10.1007/s00216-012-6307-x [doi] AB - A portable instrument for oxygen determination, based on the quenching of phosphorescent octaethylporphyrin by gaseous O(2), has been developed using the fluorimetric paired emitter-detector diode technique (FPEDD). The instrument configuration consists of two light-emitting diodes (LEDs) facing each other, with an interchangeable support containing a phosphorescent membrane in between, in which one of the LEDs is used as the light source (emitter LED) and the other, working in reverse bias mode, as the light detector. The feasibility of using a LED as a luminescence detector is studied. Its small size enables integration of the instrument into a portable measurement system. A systematic study of the system capabilities as a portable instrument was performed to optimize range, sensitivity, short term and long term stability, dynamic behaviour, effect of temperature and humidity, and temporal drift. FAU - Perez de Vargas-Sansalvador, I M AU - Perez de Vargas-Sansalvador IM AD - Department of Analytical Chemistry, Faculty of Sciences, Campus Fuentenueva, University of Granada, 18071 Granada, Spain. FAU - Fay, C AU - Fay C FAU - Fernandez-Ramos, M D AU - Fernandez-Ramos MD FAU - Diamond, D AU - Diamond D FAU - Benito-Lopez, F AU - Benito-Lopez F FAU - Capitan-Vallvey, L F AU - Capitan-Vallvey LF LA - eng PT - Journal Article DEP - 20120816 PL - Germany TA - Anal Bioanal Chem JT - Analytical and bioanalytical chemistry JID - 101134327 EDAT- 2012/08/17 06:00 MHDA- 2012/08/17 06:01 CRDT- 2012/08/17 06:00 PHST- 2012/04/15 00:00 [received] PHST- 2012/07/27 00:00 [accepted] PHST- 2012/06/19 00:00 [revised] PHST- 2012/08/17 06:00 [entrez] PHST- 2012/08/17 06:00 [pubmed] PHST- 2012/08/17 06:01 [medline] AID - 10.1007/s00216-012-6307-x [doi] PST - ppublish SO - Anal Bioanal Chem. 2012 Dec;404(10):2851-8. doi: 10.1007/s00216-012-6307-x. Epub 2012 Aug 16.