PMID- 22899164 OWN - NLM STAT- MEDLINE DCOM- 20130122 LR - 20161125 IS - 2040-3372 (Electronic) IS - 2040-3364 (Linking) VI - 4 IP - 19 DP - 2012 Sep 28 TI - Densely aligned rutile TiO2 nanorod arrays with high surface area for efficient dye-sensitized solar cells. PG - 5872-9 LID - 10.1039/c2nr31431b [doi] AB - One-dimensional (1-D) TiO(2) nanorod arrays (NRAs) with large inner surface area are desired in dye-sensitized solar cells (DSSCs). So far, good performance of DSSCs based on 1-D rutile TiO(2) NRAs remains a challenge mainly owing to their low dye-loading ability resulting from the insufficient specific surface area of 1-D TiO(2) nanostructures. In this paper, densely aligned TiO(2) NRAs with tunable thickness were grown directly on transparent conductive fluorine-doped tin oxide (FTO) substrates by hydrothermal method, followed by a facile chemical etching route to further increase the specific surface area of the TiO(2) NRAs. The etching treatment leads to the split of TiO(2) nanorods into secondary nanorods with a reduced diameter, which markedly enlarges the inner surface area of the TiO(2) NRAs. The formation of 1-D rutile TiO(2) nanotube arrays (NTAs) is observed as well in the etched TiO(2) films. Finally, a DSSC efficiency of 5.94% was achieved by utilizing an etched TiO(2) NRA as the photoanode, which is so far the best DSSC efficiency that has been reported for the 1-D rutile TiO(2) NRA films. FAU - Lv, Miaoqiang AU - Lv M AD - State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, People's Republic of China. FAU - Zheng, Dajiang AU - Zheng D FAU - Ye, Meidan AU - Ye M FAU - Sun, Lan AU - Sun L FAU - Xiao, Jing AU - Xiao J FAU - Guo, Wenxi AU - Guo W FAU - Lin, Changjian AU - Lin C LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120817 PL - England TA - Nanoscale JT - Nanoscale JID - 101525249 RN - 0 (Coloring Agents) RN - 0 (Tin Compounds) RN - 15FIX9V2JP (titanium dioxide) RN - 284SYP0193 (Fluorine) RN - D1JT611TNE (Titanium) RN - KM7N50LOS6 (stannic oxide) SB - IM MH - Coloring Agents/*chemistry MH - Fluorine/chemistry MH - Nanotubes/*chemistry/ultrastructure MH - *Solar Energy MH - Surface Properties MH - Tin Compounds/chemistry MH - Titanium/*chemistry EDAT- 2012/08/18 06:00 MHDA- 2013/01/23 06:00 CRDT- 2012/08/18 06:00 PHST- 2012/08/18 06:00 [entrez] PHST- 2012/08/18 06:00 [pubmed] PHST- 2013/01/23 06:00 [medline] AID - 10.1039/c2nr31431b [doi] PST - ppublish SO - Nanoscale. 2012 Sep 28;4(19):5872-9. doi: 10.1039/c2nr31431b. Epub 2012 Aug 17.