PMID- 22928753
OWN - NLM
STAT- MEDLINE
DCOM- 20130208
LR  - 20120925
IS  - 1936-086X (Electronic)
IS  - 1936-0851 (Linking)
VI  - 6
IP  - 9
DP  - 2012 Sep 25
TI  - A facile route to recover intrinsic graphene over large scale.
PG  - 7781-8
AB  - The intrinsic properties of initially p-type doped graphene (grown by chemical 
      vapor deposition (CVD)) can be recovered by buffered oxide etch (BOE) treatment, 
      and the dominant factor governing p-type doping is identified as the H(2)O/O(2) 
      redox system. Semi-ionic C-F bonding prevents the reaction between the products 
      of the H(2)O/O(2) redox system and graphene. BOE-treated graphene field effect 
      transistors (FETs) subsequently exposed to air, became p-type doped due to 
      recovery of the H(2)O/O(2) redox system. In comparison, poly(methyl methacrylate) 
      (PMMA)-coated graphene FETs had improved stability for maintaining the intrinsic 
      graphene electronic properties.
FAU - Shin, Dong-Wook
AU  - Shin DW
AD  - SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, 300 
      Chunchun-dong, Jangan-gu, Suwon 440746, Republic of Korea.
FAU - Lee, Hyun Myoung
AU  - Lee HM
FAU - Yu, Seong Man
AU  - Yu SM
FAU - Lim, Kwang-Soo
AU  - Lim KS
FAU - Jung, Jae Hoon
AU  - Jung JH
FAU - Kim, Min-Kyu
AU  - Kim MK
FAU - Kim, Sang-Woo
AU  - Kim SW
FAU - Han, Jae-Hee
AU  - Han JH
FAU - Ruoff, Rodney S
AU  - Ruoff RS
FAU - Yoo, Ji-Beom
AU  - Yoo JB
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PT  - Research Support, U.S. Gov't, Non-P.H.S.
DEP - 20120905
PL  - United States
TA  - ACS Nano
JT  - ACS nano
JID - 101313589
RN  - 0 (Oxides)
RN  - 7782-42-5 (Graphite)
SB  - IM
MH  - Electric Conductivity
MH  - Graphite/*chemistry/*isolation & purification
MH  - Materials Testing
MH  - Nanostructures/*chemistry/*ultrastructure
MH  - Oxides/*chemistry
MH  - Particle Size
EDAT- 2012/08/30 06:00
MHDA- 2013/02/09 06:00
CRDT- 2012/08/30 06:00
PHST- 2012/08/30 06:00 [entrez]
PHST- 2012/08/30 06:00 [pubmed]
PHST- 2013/02/09 06:00 [medline]
AID - 10.1021/nn3017603 [doi]
PST - ppublish
SO  - ACS Nano. 2012 Sep 25;6(9):7781-8. doi: 10.1021/nn3017603. Epub 2012 Sep 5.