PMID- 23054775 OWN - NLM STAT- MEDLINE DCOM- 20130702 LR - 20211021 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 20 IP - 5 DP - 2013 May TI - Spatial gradients of OCPs in European butter--integrating environmental and exposure information. PG - 2948-62 LID - 10.1007/s11356-012-1209-1 [doi] AB - The Stockholm Convention and the Global Monitoring Plan encourage the production of monitoring data to effectively evaluate the presence of the persistent organic pollutants (POPs) in all regions, in order to identify changes in levels over time, as well as to provide information on their regional and global environmental transport. Here, we report the first step of two to investigate whether butter is a feasible matrix to screen with the purpose to reflect regional ambient atmospheric air levels of POPs. The first step described here is to generate monitoring data; the second is to investigate the relationship between the two matrixes, i.e., POP concentrations in air and butter, which will be reported in another article published in this journal. Here, the 27 organochlorine pesticides listed under the Stockholm Convention have been analyzed in 75 butter samples from Europe. The general conclusions were as follows: Total organochlorine pesticide concentration is lower in butter from northern and central Europe. The spatial gradient of 1,1,1-trichloro-2,2-di(4-chlorophenyl)ethane and hexachlorocyclohexane is increasing in the eastern region of Europe (Romania, Bulgaria, and Ukraine), dieldrin towards France, and endosulfan levels were elevated on the Azores Island in the Atlantic Ocean. One butter sample from Romania exceeded the European Maximum Residue Limit value for lindane, but the other butter pesticide levels were all below the limit values. The dataset reported here can be used for the calibration of the air-grass-dairy products model, which would support the feasibility to use butter as biomonitor for measuring POP levels in ambient air. FAU - Weiss, Jana AU - Weiss J AD - Institute for Environmental Studies, VU University, De Boelelaan 1087, 1081HV Amsterdam, The Netherlands. FAU - Muller, Anne AU - Muller A FAU - Vives, Ingrid AU - Vives I FAU - Mariani, Giulio AU - Mariani G FAU - Umlauf, Gunther AU - Umlauf G LA - eng PT - Evaluation Study PT - Journal Article DEP - 20120930 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Environmental Pollutants) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticide Residues) RN - 8029-34-3 (Butter) SB - IM MH - Butter/*analysis MH - Chromatography, Gas MH - Chromatography, Gel MH - *Environmental Exposure MH - Environmental Monitoring/*methods MH - Environmental Pollutants/*analysis MH - Food Contamination/*analysis MH - Geography MH - Humans MH - Hydrocarbons, Chlorinated/*analysis MH - Pesticide Residues/*analysis MH - Seasons MH - Solid Phase Extraction EDAT- 2012/10/12 06:00 MHDA- 2013/07/03 06:00 CRDT- 2012/10/12 06:00 PHST- 2012/06/01 00:00 [received] PHST- 2012/09/17 00:00 [accepted] PHST- 2012/10/12 06:00 [entrez] PHST- 2012/10/12 06:00 [pubmed] PHST- 2013/07/03 06:00 [medline] AID - 10.1007/s11356-012-1209-1 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2013 May;20(5):2948-62. doi: 10.1007/s11356-012-1209-1. Epub 2012 Sep 30.