PMID- 23103458
OWN - NLM
STAT- MEDLINE
DCOM- 20130531
LR  - 20131121
IS  - 1873-3557 (Electronic)
IS  - 1386-1425 (Linking)
VI  - 101
DP  - 2013 Jan 15
TI  - Synthesis, structural, spectroscopic and optical studies of charge transfer 
      complex salts.
PG  - 178-83
LID - S1386-1425(12)00843-8 [pii]
LID - 10.1016/j.saa.2012.08.086 [doi]
AB  - New charge transfer molecular complex adducts of picric acid (C6H3N3O7) with 
      triethylamine (C6H15N) and dimethylformamide (HCON(CH3)2) were synthesized 
      successfully for the first time. Chemical composition and stoichiometry of the 
      synthesized complex salts were verified by CHN elemental analysis. Solubility of 
      the complex salts have been determined by gravimetric method and single crystals 
      of two new salts were grown by low temperature solution growth technique. Crystal 
      system, crystalline nature and cell parameters of the grown crystals were 
      determined by single crystal X-ray diffraction (SXRD) and powder X-ray 
      diffraction (PXRD) analyses. The formations of the charge-transfer complex, 
      functional groups and the modes of vibrations have been confirmed by Fourier 
      transform infrared (FTIR) spectroscopy. In order to know the linear and nonlinear 
      optical suitability for device fabrication, UV-Vis (UV) spectral analysis and 
      relative second harmonic generation (SHG) efficiency test were performed for the 
      grown crystals.
CI  - Copyright (c) 2012 Elsevier B.V. All rights reserved.
FAU - Manikandan, Maruthappan
AU  - Manikandan M
AD  - Department of Physics, Alagappa University, Karaikudi 630 003, India.
FAU - Mahalingam, Thaiyan
AU  - Mahalingam T
FAU - Hayakawa, Yasuhiro
AU  - Hayakawa Y
FAU - Ravi, Ganesan
AU  - Ravi G
LA  - eng
PT  - Journal Article
DEP - 20120912
PL  - England
TA  - Spectrochim Acta A Mol Biomol Spectrosc
JT  - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
JID - 9602533
RN  - 0 (Ethylamines)
RN  - 0 (Picrates)
RN  - 0 (Salts)
RN  - 8696NH0Y2X (Dimethylformamide)
RN  - A49OS0F91S (picric acid)
RN  - VOU728O6AY (triethylamine)
SB  - IM
MH  - Crystallization
MH  - Crystallography, X-Ray
MH  - Dimethylformamide/chemical synthesis/*chemistry
MH  - Ethylamines/chemical synthesis/*chemistry
MH  - Picrates/chemical synthesis/*chemistry
MH  - Salts/chemical synthesis/*chemistry
MH  - Spectrophotometry, Ultraviolet
MH  - Spectroscopy, Fourier Transform Infrared
EDAT- 2012/10/30 06:00
MHDA- 2013/06/01 06:00
CRDT- 2012/10/30 06:00
PHST- 2012/06/04 00:00 [received]
PHST- 2012/08/27 00:00 [revised]
PHST- 2012/08/31 00:00 [accepted]
PHST- 2012/10/30 06:00 [entrez]
PHST- 2012/10/30 06:00 [pubmed]
PHST- 2013/06/01 06:00 [medline]
AID - S1386-1425(12)00843-8 [pii]
AID - 10.1016/j.saa.2012.08.086 [doi]
PST - ppublish
SO  - Spectrochim Acta A Mol Biomol Spectrosc. 2013 Jan 15;101:178-83. doi: 
      10.1016/j.saa.2012.08.086. Epub 2012 Sep 12.