PMID- 23104302 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20131023 LR - 20130422 IS - 1364-548X (Electronic) IS - 1359-7345 (Linking) VI - 49 IP - 39 DP - 2013 May 14 TI - [Cu30I16(mtpmt)12(mu(10-S4))]: an unusual 30-membered copper(I) cluster derived from the C-S bond cleavage and its use in heterogeneous catalysis. PG - 4259-61 LID - 10.1039/c2cc36736j [doi] AB - The Cu(I)-mediated C-S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2-thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt)12(mu10-S4)], one polymeric complex [(bmtpms)Cu-(mu-I)]n and one tetranuclear complex [(bmptmds)Cu(mu-I)2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused. FAU - Li, Hong-Xi AU - Li HX AD - College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, Jiangsu, PR China. lihx@suda.edu.cn FAU - Zhao, Wei AU - Zhao W FAU - Li, Hai-Yan AU - Li HY FAU - Xu, Zhong-Lin AU - Xu ZL FAU - Wang, Wen-Xia AU - Wang WX FAU - Lang, Jian-Ping AU - Lang JP LA - eng PT - Journal Article DEP - 20121029 PL - England TA - Chem Commun (Camb) JT - Chemical communications (Cambridge, England) JID - 9610838 EDAT- 2012/10/30 06:00 MHDA- 2012/10/30 06:01 CRDT- 2012/10/30 06:00 PHST- 2012/10/30 06:00 [entrez] PHST- 2012/10/30 06:00 [pubmed] PHST- 2012/10/30 06:01 [medline] AID - 10.1039/c2cc36736j [doi] PST - ppublish SO - Chem Commun (Camb). 2013 May 14;49(39):4259-61. doi: 10.1039/c2cc36736j. Epub 2012 Oct 29.