PMID- 23108756 OWN - NLM STAT- MEDLINE DCOM- 20130702 LR - 20211021 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 20 IP - 5 DP - 2013 May TI - Organochlorine pesticides and polychlorinated biphenyls in soils surrounding the Tanggu Chemical Industrial District of Tianjin, China. PG - 3366-80 LID - 10.1007/s11356-012-1260-y [doi] AB - The spatial distribution of persistent organic pollutants (POPs) was examined in soils surrounding the Tanggu Chemical Industrial District in Tianjin, China. The concentrations of hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs), hexachlorobenzenes (HCBs), and polychlorinated biphenyls (PCBs) were determined in 70 surface soils using accelerated solvent extraction and gas chromatography with electron capture detection. The results showed that the ranges of summation operatorHCH, summation operatorDDT, SigmaHCB, and summation operatorPCB concentrations in soils were 2.1-12,549 mug kg(-1) (average, 965 mug kg(-1)), n.d.-2,033 mug kg(-1) (average, 88.4 mug kg(-1)), n.d.-1,924 mug kg(-1) (average, 349 mug kg(-1)), and n.d.-373 mug kg(-1) (average, 46.2 mug kg(-1)), respectively. Of these, HCHs were the dominant POPs, accounting for 75 % of the total organochlorine pesticide (OCP) residues. Overall, the spatial distribution of OCP concentrations showed a decreasing trend from the center of the Tanggu District to the surrounding areas. Two major pollution sources were Tianjin Dagu Chemical Co., Ltd. in the district center and the Tianjin Chemical Plant in Hangu District. In contrast, PCB concentrations were relatively high in the Haihe estuary to the east and low to the west of the study area. Component analysis of OCPs in these soils showed that they mainly came from industrial point sources. Compared with soils in other regions, soil DDT pollution was at a medium level in the Tanggu Chemical Industrial District, but associated HCH, HCB, and PCB pollution was relatively heavy. By multivariate statistical analyses, Tianjin Dagu Chemical Co., Ltd. was recognized as the main source of POPs, and soil properties were clarified to play an important role on the distribution and composition of POPs, especially the organic carbon content. FAU - Hou, Hong AU - Hou H AD - State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Dayangfang 8, Beijing 100012, People's Republic of China. houhong@craes.org.cn FAU - Zhao, L AU - Zhao L FAU - Zhang, J AU - Zhang J FAU - Xu, Y F AU - Xu YF FAU - Yan, Z G AU - Yan ZG FAU - Bai, L P AU - Bai LP FAU - Li, F S AU - Li FS LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20121030 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticide Residues) RN - 0 (Soil Pollutants) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - China MH - Environmental Monitoring MH - Gas Chromatography-Mass Spectrometry MH - Hydrocarbons, Chlorinated/*analysis MH - Multivariate Analysis MH - Pesticide Residues/*analysis MH - Polychlorinated Biphenyls/*analysis MH - Soil Pollutants/*analysis EDAT- 2012/10/31 06:00 MHDA- 2013/07/03 06:00 CRDT- 2012/10/31 06:00 PHST- 2012/06/11 00:00 [received] PHST- 2012/10/10 00:00 [accepted] PHST- 2012/10/31 06:00 [entrez] PHST- 2012/10/31 06:00 [pubmed] PHST- 2013/07/03 06:00 [medline] AID - 10.1007/s11356-012-1260-y [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2013 May;20(5):3366-80. doi: 10.1007/s11356-012-1260-y. Epub 2012 Oct 30.