PMID- 23194353
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20130530
LR  - 20121217
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 51
IP  - 24
DP  - 2012 Dec 17
TI  - Ionothermal synthesis of four new nickel thiophosphate anions: [Ni(P2S8)2]2-, 
      [Ni(P3S9)(P2S8)]3-, [Ni(P3S9)2]4-, and [(NiP3S8)4(PS4)]7-.
PG  - 13357-62
LID - 10.1021/ic302112g [doi]
AB  - Four new nickel thiophosphate anions have been isolated as 
      1-ethyl-3-methylimidazolium (EMIM) salts: [EMIM](2)[Ni(P(2)S(8))(2)] (1), 
      [EMIM](3)[Ni(P(3)S(9))(P(2)S(8))] (2), [EMIM](4)[Ni(P(3)S(9))(2)] (3), and 
      [EMIM](7)[(NiP(3)S(8))(4)(PS(4))] (4). Single crystals of each were prepared by 
      ionothermal reaction of the elements in [EMIM][BF(4)]. 1 can also be obtained 
      from [EMIM][CF(3)SO(3)]. In all four anions, Ni atoms are octahedrally 
      coordinated and P atoms are tetrahedrally coordinated. In the anion found in 1, 
      two tridentate 1,3-P(2)S(8)(2-) ligands are cis to each other. The anion in 2 
      contains two different tridentate thiophosphate ligands, 1,3-P(2)S(8)(2-) and 
      P(3)S(9)(3-), whereas the anion in 3 consists of two P(3)S(9)(3-) ligands 
      coordinated to the central Ni atom. The anion in 4 is complex, consisting of four 
      NiP(3)S(8)(-) clusters surrounding a central PS(4) tetrahedron; within the 
      NiP(3)S(8)(-) groups, one P atom is directly bound to Ni. The discovery of these 
      four new compounds demonstrates the versatility of ionothermal methods for the 
      synthesis of novel thiophosphates.
FAU - Cody, Jason A
AU  - Cody JA
AD  - Department of Chemistry, Lake Forest College, 555 North Sheridan Road, Lake 
      Forest, Illinois 60045, United States. cody@lakeforest.edu
FAU - Finch, Kenneth B
AU  - Finch KB
FAU - Reynders, Gilbert J 3rd
AU  - Reynders GJ 3rd
FAU - Alexander, Grant C B
AU  - Alexander GC
FAU - Lim, Hyung G
AU  - Lim HG
FAU - Nather, Christian
AU  - Nather C
FAU - Bensch, Wolfgang
AU  - Bensch W
LA  - eng
PT  - Journal Article
DEP - 20121129
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
EDAT- 2012/12/01 06:00
MHDA- 2012/12/01 06:01
CRDT- 2012/12/01 06:00
PHST- 2012/12/01 06:00 [entrez]
PHST- 2012/12/01 06:00 [pubmed]
PHST- 2012/12/01 06:01 [medline]
AID - 10.1021/ic302112g [doi]
PST - ppublish
SO  - Inorg Chem. 2012 Dec 17;51(24):13357-62. doi: 10.1021/ic302112g. Epub 2012 Nov 
      29.