PMID- 23194542
OWN - NLM
STAT- MEDLINE
DCOM- 20130517
LR  - 20191210
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 136
IP  - 3-4
DP  - 2013 Feb 15
TI  - Simple multiresidue extraction method for the determination of fungicides and 
      plant growth regulator in bean sprouts using low temperature partitioning and 
      tandem mass spectrometry.
PG  - 1414-20
LID - S0308-8146(12)01472-0 [pii]
LID - 10.1016/j.foodchem.2012.09.068 [doi]
AB  - A simple multiresidue analytical method is developed for the simultaneous 
      determination of carbendazim (CB), thiabendazole (TB), and 6-benzyl aminopurine 
      (6-BA) in bean sprouts. The samples were extracted with acetonitrile followed by 
      partitioning at -80 degrees C for 5-10 min. A YMC C(8) column was used to separate the 
      analytes before being qualitatively and quantitatively determined by liquid 
      chromatography-electrospray ionization tandem mass spectrometry (LC-ESI-MS/MS) in 
      positive ion mode using multiple reaction monitoring (MRM). The matrix-matched 
      calibration curves showed good linearity in the range 0.01-1.0 mg/kg with 
      correlation coefficients in excess of 0.998. The mean recoveries were in the 
      range of 80.4-96.3% at 0.1 and 0.5 spiked levels, and the relative standard 
      deviations (RSDs) were in the range of 0.5-7.6%. The limits of quantifications 
      (LOQ) were in the range of 0.005-0.01 mg/kg. The method was successfully applied 
      to 90 samples (among which 45 were organic) collected from a commercial bean 
      sprout production house throughout the city. Except for 6-BA, the rest of the 
      analytes had values lower than their LOQs. In sum, carbendazim, thiabendazole, 
      and 6-BA were extracted in a single step, and no steps for clean-up or 
      concentration of the extracts were needed. The current method can be used for 
      sensitive and accurate determination and confirmation of residues in bean sprout 
      samples.
CI  - Copyright (c) 2012 Elsevier Ltd. All rights reserved.
FAU - Cho, Soon-Kil
AU  - Cho SK
AD  - National Agricultural Products Quality Management Service, Products Safety 
      Inspection Laboratory, Gwangsan-Gu, Gwangju, Republic of Korea.
FAU - Abd El-Aty, A M
AU  - Abd El-Aty AM
FAU - Park, Ki Hun
AU  - Park KH
FAU - Park, Jong-Hyouk
AU  - Park JH
FAU - Assayed, M E
AU  - Assayed ME
FAU - Jeong, Yang-Mo
AU  - Jeong YM
FAU - Park, Young-Seok
AU  - Park YS
FAU - Shim, Jae-Han
AU  - Shim JH
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
DEP - 20120928
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Fungicides, Industrial)
RN  - 0 (Pesticide Residues)
RN  - 0 (Plant Growth Regulators)
SB  - IM
MH  - Chemical Fractionation/*methods
MH  - Chromatography, High Pressure Liquid/methods
MH  - Chromatography, Liquid
MH  - Fabaceae/*chemistry
MH  - Food Contamination/analysis
MH  - Fungicides, Industrial/*analysis/*isolation & purification
MH  - Pesticide Residues/*analysis/*isolation & purification
MH  - Plant Growth Regulators/*analysis/*isolation & purification
MH  - Spectrometry, Mass, Electrospray Ionization/methods
MH  - Tandem Mass Spectrometry
MH  - Vegetables/chemistry
EDAT- 2012/12/01 06:00
MHDA- 2013/05/18 06:00
CRDT- 2012/12/01 06:00
PHST- 2012/07/08 00:00 [received]
PHST- 2012/09/04 00:00 [revised]
PHST- 2012/09/12 00:00 [accepted]
PHST- 2012/12/01 06:00 [entrez]
PHST- 2012/12/01 06:00 [pubmed]
PHST- 2013/05/18 06:00 [medline]
AID - S0308-8146(12)01472-0 [pii]
AID - 10.1016/j.foodchem.2012.09.068 [doi]
PST - ppublish
SO  - Food Chem. 2013 Feb 15;136(3-4):1414-20. doi: 10.1016/j.foodchem.2012.09.068. 
      Epub 2012 Sep 28.