PMID- 23213920 OWN - NLM STAT- MEDLINE DCOM- 20131205 LR - 20161018 IS - 0250-3301 (Print) IS - 0250-3301 (Linking) VI - 33 IP - 8 DP - 2012 Aug TI - [Adsorption characteristics and mechanism of uranium on attapulgite]. PG - 2889-94 AB - The adsorption characteristics of uranium on attapulgite were investigated by conducting a series of batch adsorption experiments in this study. The influence of solution pH, initial uranium concentration and contact time was investigated. Scanning electron microscope (SEM) and X-ray diffraction (XRD) were used to characterize the surface structure of the attapulgite, Fourier transform infrared spectrometer (FTIR) were used to characterize the surface properties of the attapulgite before and after uranium adsorption, and to analyze the adsorption mechanism and adsorption kinetics of uranium on attapulgite. The experimental results showed that sorption of uranium on attapulgite was strongly dependent on pH, and the highest adsorption reached at pH = 5. The adsorption quantity increased with time, adsorption could achieve balance in 2 h. The adsorption isotherm equation conformed to the Langmuir isothermal adsorption model and adsorption process could be described by the two-order kinetics model. According to FTIR spectral, the absorbance of attapulgite decreased, which may result from R--OUO2+ or (R--O)2UO2 formed by the bond between uranium and R-OH of attapulgite in the high frequency area 3700-3000 cm(-1), and which uranium ion and magnesium ions may produce ion exchanges in the intermediate frequency area 1700-800 cm(-1). Adsorption mechanism of uranium on attapulgite was mainly ion exchange and complexation. FAU - Liu, Juan AU - Liu J AD - School of Environmental Science & Engineering, Guangzhou University, Guangzhou 510006, China. lj_brave@hotmail.com FAU - Chen, Di-yun AU - Chen DY FAU - Zhang, Jing AU - Zhang J FAU - Song, Gang AU - Song G FAU - Luo, Ding-gui AU - Luo DG LA - chi PT - English Abstract PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - China TA - Huan Jing Ke Xue JT - Huan jing ke xue= Huanjing kexue JID - 8405344 RN - 0 (Magnesium Compounds) RN - 0 (Silicon Compounds) RN - 0 (Soil Pollutants, Radioactive) RN - 4OC371KSTK (Uranium) RN - U6V729APAM (attapulgite) SB - IM MH - Adsorption MH - Hydrogen-Ion Concentration MH - Kinetics MH - Magnesium Compounds/*chemistry MH - Silicon Compounds/*chemistry MH - Soil Pollutants, Radioactive/chemistry/*isolation & purification MH - Uranium/chemistry/*isolation & purification EDAT- 2012/12/12 06:00 MHDA- 2013/12/16 06:00 CRDT- 2012/12/11 06:00 PHST- 2012/12/11 06:00 [entrez] PHST- 2012/12/12 06:00 [pubmed] PHST- 2013/12/16 06:00 [medline] PST - ppublish SO - Huan Jing Ke Xue. 2012 Aug;33(8):2889-94.