PMID- 23256387
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20130808
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 30
IP  - 8
DP  - 2012 Aug
TI  - [Trace analysis of heavy metal ions in electroplate waste water by capillary 
      electrophoresis with visual offline sample stacking via moving neutralization 
      boundary].
PG  - 827-31
AB  - A moving neutralization boundary (MNB) was developed as a novel model of visual 
      offline sample stacking for the trace analysis of heavy metal ions (HMIs) by 
      capillary zone electrophoresis (CZE). In the stacking system, the motion 
      direction of MNB to cathode was used with 2.1 mmol/L HCl-98 mmol/L KCl-trace 
      metal ions in the anodic solution and 4.0 mmol/L NaOH-96 mmol/L KCl in the 
      cathodic solution. The voltage was constant at 180 V and the flow rate of the 
      anolyte and catholyte was 1 mL/min. The metal ions in the gel after stacking were 
      detected by capillary electrophoresis. The calibration curves showed good linear 
      relationship (r > or = 0.998 5) in the concentration range used in the 
      experiments. The pre-concentration factors were up to 80 - 150 and the limits of 
      detection (LODs) were 0.163, 0.256, 0.077, 0.153, 0.203, 0.062 and 0.142 mg/L for 
      Cu(II), Zn(II), Ni(II), Mg(II), Ca(II), Cr(III) and Fe(III), respectively, 
      obviously lower than the national standards. The intra-day and inter-day assay 
      precisions were good (the relative standard deviations (RSDs) less than 7.42%). 
      Finally, the developed method has been successfully used for the stacking and the 
      detection of heavy metal ions in electroplate waste water.
FAU - Fan, Yinping
AU  - Fan Y
AD  - School of Bioscience and Bioengineering, South China University of Technology, 
      Guangzhou 510006, China.
FAU - Li, Shan
AU  - Li S
FAU - Fan, Liuyin
AU  - Fan L
FAU - Cao, Chengxi
AU  - Cao C
LA  - chi
PT  - English Abstract
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
EDAT- 2012/12/22 06:00
MHDA- 2012/12/22 06:01
CRDT- 2012/12/22 06:00
PHST- 2012/12/22 06:00 [entrez]
PHST- 2012/12/22 06:00 [pubmed]
PHST- 2012/12/22 06:01 [medline]
AID - 10.3724/sp.j.1123.2012.04003 [doi]
PST - ppublish
SO  - Se Pu. 2012 Aug;30(8):827-31. doi: 10.3724/sp.j.1123.2012.04003.