PMID- 23312333
OWN - NLM
STAT- MEDLINE
DCOM- 20130620
LR  - 20161125
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 761
DP  - 2013 Jan 25
TI  - Polyhedral oligomeric silsesquioxanes as functional monomer to prepare hybrid 
      monolithic columns for capillary electrochromatography and capillary liquid 
      chromatography.
PG  - 209-16
LID - S0003-2670(12)01729-1 [pii]
LID - 10.1016/j.aca.2012.11.052 [doi]
AB  - A simple approach to fabricate hybrid monolithic column within the confines of 
      fused-silica capillaries (75 mum i.d.) was introduced. A polyhedral oligomeric 
      silsesquioxanes (POSS) reagent containing a methacrylate group was selected as 
      functional monomer, and copolymerized with bisphenol A dimethacrylate (BPADMA) or 
      ethylene dimethacrylate (EDMA) in the presence of porogenic solvents via 
      thermally initiated free radical polymerization. After optimization of the 
      preparation conditions, two POSS-containing hybrid monoliths were successfully 
      prepared and exhibited good permeability and stability. By comparison of the 
      separation efficiencies of the resulting poly(POSS-co-BPADMA) and 
      poly(POSS-co-EDMA) monoliths in capillary electrochromatography (CEC) and 
      capillary liquid chromatography (cLC), it was indicated the former has better 
      column efficiencies for alkylbenzenes, phenols, anilines and PAHs in CEC and cLC 
      than the latter. Particularly, the hybrid poly(POSS-co-BPADMA) monolith is more 
      suitable for separation of PAHs due to pi-pi interaction between the analytes and 
      aromatic rings in the surface of monolithic stationary phase.
CI  - Copyright (c) 2012 Elsevier B.V. All rights reserved.
FAU - Ou, Junjie
AU  - Ou J
AD  - CAS Key Laboratory of Separation Science for Analytical Chemistry, National 
      Chromatographic R & A Center, Dalian Institute of Chemical Physics, Chinese 
      Academy of Sciences (CAS), Dalian 116023, China. junjieou@dicp.ac.cn
FAU - Zhang, Zhenbin
AU  - Zhang Z
FAU - Lin, Hui
AU  - Lin H
FAU - Dong, Jing
AU  - Dong J
FAU - Zou, Hanfa
AU  - Zou H
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20121205
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Aniline Compounds)
RN  - 0 (Benzene Derivatives)
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Methacrylates)
RN  - 0 (Organosilicon Compounds)
RN  - 0 (Phenols)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (polyhedraloligosilsesquioxane)
RN  - 7BK5G69305 (ethylene dimethacrylate)
RN  - 982O8255NE (2,2-di(4-methacryloxyphenyl)propane)
SB  - IM
MH  - Aniline Compounds/isolation & purification
MH  - Benzene Derivatives/isolation & purification
MH  - Benzhydryl Compounds/*chemistry
MH  - Capillary Electrochromatography/*instrumentation
MH  - Methacrylates/*chemistry
MH  - Organosilicon Compounds/*chemistry
MH  - Phenols/isolation & purification
MH  - Polycyclic Aromatic Hydrocarbons/isolation & purification
MH  - Polymerization
EDAT- 2013/01/15 06:00
MHDA- 2013/06/21 06:00
CRDT- 2013/01/15 06:00
PHST- 2012/09/16 00:00 [received]
PHST- 2012/11/07 00:00 [revised]
PHST- 2012/11/27 00:00 [accepted]
PHST- 2013/01/15 06:00 [entrez]
PHST- 2013/01/15 06:00 [pubmed]
PHST- 2013/06/21 06:00 [medline]
AID - S0003-2670(12)01729-1 [pii]
AID - 10.1016/j.aca.2012.11.052 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2013 Jan 25;761:209-16. doi: 10.1016/j.aca.2012.11.052. Epub 2012 
      Dec 5.