PMID- 23380055 OWN - NLM STAT- MEDLINE DCOM- 20130625 LR - 20130205 IS - 1355-0306 (Print) IS - 1355-0306 (Linking) VI - 53 IP - 1 DP - 2013 Mar TI - Determining the order of deposition of natural latent fingerprints and laser printed ink using chemical mapping with secondary ion mass spectrometry. PG - 2-7 LID - S1355-0306(12)00072-X [pii] LID - 10.1016/j.scijus.2012.05.007 [doi] AB - Time-of-flight secondary ion mass spectrometry (ToF-SIMS) chemical mapping was used to investigate the order of deposition of natural latent fingerprints and laser printed ink on paper. This feasibility study shows that sodium, potassium and C(3)H(5) positive ions were particularly abundant endogenous components of the natural fingerprints and also present in the paper examined, but were mostly absent in the laser printed ink. Mapping of these ions enables the observation of friction ridges from latent prints on the ink surface, only when a fingerprint was deposited above the layer of ink. As a demonstration of proof of concept, blind testing of 21 samples from three donors resulted in a 100% success rate. The sensitivity of this technique was investigated within this trial through the examination of up to fifth depletion fingerprints and ageing of up to 28 days. Migration of fingerprint and paper components to the ink surface, although observed with increased ageing time, was not found to compromise determination of the deposition sequence. CI - Copyright (c) 2012. Published by Elsevier Ireland Ltd. FAU - Attard Montalto, Nicola AU - Attard Montalto N AD - Brunel University, Uxbridge, UK. FAU - Ojeda, Jesus J AU - Ojeda JJ FAU - Jones, Benjamin J AU - Jones BJ LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120628 PL - England TA - Sci Justice JT - Science & justice : journal of the Forensic Science Society JID - 9508563 SB - IM MH - *Dermatoglyphics MH - Feasibility Studies MH - Humans MH - *Ink MH - Mass Spectrometry MH - Microscopy, Electron, Scanning MH - *Paper MH - Sebum/*chemistry EDAT- 2013/02/06 06:00 MHDA- 2013/06/26 06:00 CRDT- 2013/02/06 06:00 PHST- 2012/02/14 00:00 [received] PHST- 2012/05/23 00:00 [revised] PHST- 2012/05/25 00:00 [accepted] PHST- 2013/02/06 06:00 [entrez] PHST- 2013/02/06 06:00 [pubmed] PHST- 2013/06/26 06:00 [medline] AID - S1355-0306(12)00072-X [pii] AID - 10.1016/j.scijus.2012.05.007 [doi] PST - ppublish SO - Sci Justice. 2013 Mar;53(1):2-7. doi: 10.1016/j.scijus.2012.05.007. Epub 2012 Jun 28.