PMID- 23383494
OWN - NLM
STAT- MEDLINE
DCOM- 20140502
LR  - 20231213
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 30
IP  - 10
DP  - 2012 Oct
TI  - [Determination of 132 pesticide residues in tobacco by gas chromatography-tandem 
      mass spectrometry].
PG  - 1043-55
AB  - A simple method for the determination of 132 pesticide residues in tobacco by gas 
      chromatography-triple quadrupole tandem mass spectrometry (GC-MS/MS) was 
      established. The influences of different extraction solvents, different buffer 
      systems and different purifying agents on the recoveries of pesticides were 
      investigated. The tobacco sample was extracted with acetonitrile, then cleaned up 
      by the mixed sorbents of primary secondary amine (PSA) and octadecylsilane 
      (C18E). After dried by nitrogen, the extract residue was reconstituted with 
      n-hexane-acetone (9:1, v/v). GC-MS/MS in multi-reaction monitoring (MRM) mode was 
      used as the detection method and triphenyl phosphate (TPP) as the internal 
      standard. All of the 132 pesticides had good linear relationships (r2 > 0.99) 
      between 20 microg/kg and 2 000 microg/kg. At the three spiked levels of 50, 200 
      and 500 microg/kg in the tobacco extract, the average recoveries of all the 
      pesticides were in the range of 68.10% to 123.15% except for mirex and 
      hexachlorobenzene; moreover, the relative standard deviations (RSDs) of them were 
      between 1.79% and 19.88%. We participated in the CORESTA (Cooperation Centre for 
      Scientific Research Relative to Tobacco) 2012's co-experiment. The results of our 
      method and the existed standard methods had good consistency. The accurate, 
      reliable and sensitive method can be applied to the determination of the 132 
      pesticide residues in tobacco for rapid screening and quantitative analysis.
FAU - Chen, Xiaoshui
AU  - Chen X
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou 450001, 
      China.
FAU - Bian, Zhaoyang
AU  - Bian Z
FAU - Tang, Gangling
AU  - Tang G
FAU - Hu, Qingyuan
AU  - Hu Q
LA  - chi
PT  - English Abstract
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Organophosphorus Compounds)
RN  - 0 (Pesticide Residues)
RN  - 1NQ08HN02S (Methomyl)
RN  - 7U370BPS14 (Dichlorvos)
RN  - N8RU9F1IQD (dimefox)
SB  - IM
MH  - Dichlorvos/analysis
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Methomyl/analysis
MH  - Organophosphorus Compounds/analysis
MH  - Pesticide Residues/*analysis
MH  - Tandem Mass Spectrometry/*methods
MH  - Nicotiana/*chemistry
EDAT- 2013/02/07 06:00
MHDA- 2014/05/03 06:00
CRDT- 2013/02/07 06:00
PHST- 2013/02/07 06:00 [entrez]
PHST- 2013/02/07 06:00 [pubmed]
PHST- 2014/05/03 06:00 [medline]
AID - 10.3724/sp.j.1123.2012.06031 [doi]
PST - ppublish
SO  - Se Pu. 2012 Oct;30(10):1043-55. doi: 10.3724/sp.j.1123.2012.06031.