PMID- 23473251
OWN - NLM
STAT- MEDLINE
DCOM- 20130912
LR  - 20131121
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 768
DP  - 2013 Mar 20
TI  - Preparation of cobalt-tetraphenylporphyrin/reduced graphene oxide nanocomposite 
      and its application on hydrogen peroxide biosensor.
PG  - 69-75
LID - S0003-2670(13)00167-0 [pii]
LID - 10.1016/j.aca.2013.01.019 [doi]
AB  - A novel cobalt-tetraphenylporphyrin/reduced graphene oxide (CoTPP/RGO) 
      nanocomposite was prepared by a pi-pi stacking interaction and characterized by 
      ultraviolet-visible absorption spectroscopy (UV-vis), Fourier transform infrared 
      spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS). The 
      CoTPP/RGO nanocomposite exhibited high electrocatalytic activity both for 
      oxidation and reduction of H2O2. The current response was linear to H2O2 
      concentration with the concentration range from 1.0x10(-7) to 2.4x10(-3)molL(-1) 
      (R=0.998) at the reductive potential of -0.20V and from 1.0x10(-7) to 
      4.6x10(-4)molL(-1) (R=0.996) at the oxidative potential of +0.50V. The H2O2 
      biosensor showed good anti-interfering ability towards oxidative interferences at 
      the oxidative potential of +0.50V and good anti-interfering ability towards 
      reductive interferences at the reductive potential of -0.20V.
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Zheng, Longzhen
AU  - Zheng L
AD  - Department of Chemistry and Chemical Engineering, East China Jiao Tong 
      University, Nanchang, Jiangxi 330013, PR China. zlz@ecjtu.jx.cn
FAU - Ye, Dan
AU  - Ye D
FAU - Xiong, Leyan
AU  - Xiong L
FAU - Xu, Jingpeng
AU  - Xu J
FAU - Tao, Kun
AU  - Tao K
FAU - Zou, Zhijun
AU  - Zou Z
FAU - Huang, Danlin
AU  - Huang D
FAU - Kang, Xiaowei
AU  - Kang X
FAU - Yang, Shaoming
AU  - Yang S
FAU - Xia, Jian
AU  - Xia J
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130121
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Oxides)
RN  - 0 (Porphyrins)
RN  - 0 (tetraphenylporphyrin)
RN  - 3G0H8C9362 (Cobalt)
RN  - 7782-42-5 (Graphite)
RN  - BBX060AN9V (Hydrogen Peroxide)
SB  - IM
MH  - *Biosensing Techniques
MH  - Cobalt/*chemistry
MH  - Dielectric Spectroscopy
MH  - Electrochemical Techniques
MH  - Electrodes
MH  - Graphite/*chemistry
MH  - Hydrogen Peroxide/*analysis
MH  - Nanocomposites/*chemistry
MH  - Oxidation-Reduction
MH  - Oxides/chemistry
MH  - Porphyrins/*chemistry
EDAT- 2013/03/12 06:00
MHDA- 2013/09/13 06:00
CRDT- 2013/03/12 06:00
PHST- 2012/12/02 00:00 [received]
PHST- 2013/01/08 00:00 [revised]
PHST- 2013/01/12 00:00 [accepted]
PHST- 2013/03/12 06:00 [entrez]
PHST- 2013/03/12 06:00 [pubmed]
PHST- 2013/09/13 06:00 [medline]
AID - S0003-2670(13)00167-0 [pii]
AID - 10.1016/j.aca.2013.01.019 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2013 Mar 20;768:69-75. doi: 10.1016/j.aca.2013.01.019. Epub 2013 
      Jan 21.