PMID- 23474198
OWN - NLM
STAT- MEDLINE
DCOM- 20140121
LR  - 20130705
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1300
DP  - 2013 Jul 26
TI  - Development of a home-made extraction device for vortex-assisted 
      surfactant-enhanced-emulsification liquid-liquid microextraction with lighter 
      than water organic solvents.
PG  - 58-63
LID - S0021-9673(13)00361-0 [pii]
LID - 10.1016/j.chroma.2013.02.054 [doi]
AB  - We have developed a novel vortex-assisted surfactant-enhanced-emulsification 
      liquid-liquid microextraction using the low density solvent for the determination 
      of eight organophosphorus pesticides (OPPs) in water samples. The key point of 
      this method is the application of a special home-made extraction device. The 
      influence parameters relevant to this method were systemically investigated and 
      the optimum conditions were as follow: 35muL of toluene was used as extraction 
      solvent and 0.2mmol L-1 Triton X-100 was chosen as the surfactant to enhance the 
      emulsification. Under the optimum experimental conditions, the limit of 
      detections (LODs) of the method was ranged between 0.01 and 0.05mugL(-1) and the 
      relative standard deviations (RSDs) were 2.9-8.1%. The calibration curve was 
      linear in the range of 0.1-50.0mugL(-1), with the correlation coefficients (r) 
      varying from 0.9949 to 0.9991. Finally, the developed method has been 
      successfully applied to the determination of eight organophosphorus pesticides in 
      river, reservoir and well water samples with recoveries between 82.1% and 98.7%.
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Yang, Zhong-Hua
AU  - Yang ZH
AD  - Department of Applied Chemistry, China Agricultural University, Beijing 100193, 
      China.
FAU - Wang, Peng
AU  - Wang P
FAU - Zhao, Wen-ting
AU  - Zhao WT
FAU - Zhou, Zhi-Qiang
AU  - Zhou ZQ
FAU - Liu, Dong-Hui
AU  - Liu DH
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130224
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Organothiophosphates)
RN  - 0 (Solvents)
RN  - 0 (Surface-Active Agents)
RN  - 0 (Water Pollutants, Chemical)
RN  - 3FPU23BG52 (Toluene)
RN  - 9002-93-1 (Octoxynol)
SB  - IM
MH  - Chromatography, Gas
MH  - Fresh Water/chemistry
MH  - Limit of Detection
MH  - Liquid Phase Microextraction/*instrumentation/*methods
MH  - Octoxynol/chemistry
MH  - Organothiophosphates/analysis/isolation & purification
MH  - Osmolar Concentration
MH  - Reproducibility of Results
MH  - Solvents/*chemistry
MH  - Surface-Active Agents/*chemistry
MH  - Temperature
MH  - Toluene/chemistry
MH  - Water Pollutants, Chemical/analysis/isolation & purification
OTO - NOTNLM
OT  - Gas chromatography
OT  - Liquid-liquid microextraction
OT  - Reservoir
OT  - River
OT  - Well water
EDAT- 2013/03/12 06:00
MHDA- 2014/01/22 06:00
CRDT- 2013/03/12 06:00
PHST- 2012/12/05 00:00 [received]
PHST- 2013/02/17 00:00 [revised]
PHST- 2013/02/18 00:00 [accepted]
PHST- 2013/03/12 06:00 [entrez]
PHST- 2013/03/12 06:00 [pubmed]
PHST- 2014/01/22 06:00 [medline]
AID - S0021-9673(13)00361-0 [pii]
AID - 10.1016/j.chroma.2013.02.054 [doi]
PST - ppublish
SO  - J Chromatogr A. 2013 Jul 26;1300:58-63. doi: 10.1016/j.chroma.2013.02.054. Epub 
      2013 Feb 24.