PMID- 23489053 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20130926 LR - 20130410 IS - 1520-5126 (Electronic) IS - 0002-7863 (Linking) VI - 135 IP - 14 DP - 2013 Apr 10 TI - Controlled synthesis of highly crystalline MoS2 flakes by chemical vapor deposition. PG - 5304-7 LID - 10.1021/ja4013485 [doi] AB - The controlled synthesis of highly crystalline MoS2 atomic layers remains a challenge for the practical applications of this emerging material. Here, we developed an approach for synthesizing MoS2 flakes in rhomboid shape with controlled number of layers by the layer-by-layer sulfurization of MoO2 microcrystals. The obtained MoS2 flakes showed high crystallinity with crystal domain size of ~10 mum, significantly larger than the grain size of MoS2 grown by other methods. As a result of the high crystallinity, the performance of back-gated field effect transistors (FETs) made on these MoS2 flakes was comparable to that of FETs based on mechanically exfoliated flakes. This simple approach opens up a new avenue for controlled synthesis of MoS2 atomic layers and will make this highly crystalline material easily accessible for fundamental aspects and various applications. FAU - Wang, Xinsheng AU - Wang X AD - Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China. FAU - Feng, Hongbin AU - Feng H FAU - Wu, Yongmin AU - Wu Y FAU - Jiao, Liying AU - Jiao L LA - eng PT - Journal Article DEP - 20130327 PL - United States TA - J Am Chem Soc JT - Journal of the American Chemical Society JID - 7503056 EDAT- 2013/03/16 06:00 MHDA- 2013/03/16 06:01 CRDT- 2013/03/16 06:00 PHST- 2013/03/16 06:00 [entrez] PHST- 2013/03/16 06:00 [pubmed] PHST- 2013/03/16 06:01 [medline] AID - 10.1021/ja4013485 [doi] PST - ppublish SO - J Am Chem Soc. 2013 Apr 10;135(14):5304-7. doi: 10.1021/ja4013485. Epub 2013 Mar 27.