PMID- 23498690
OWN - NLM
STAT- MEDLINE
DCOM- 20130917
LR  - 20221207
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 770
DP  - 2013 Apr 3
TI  - Application of polydimethylsiloxane rod extraction to the determination of 
      sixteen halogenated flame retardants in water samples.
PG  - 85-93
LID - S0003-2670(13)00208-0 [pii]
LID - 10.1016/j.aca.2013.01.059 [doi]
AB  - An extraction and preconcentration procedure for the determination in water 
      samples of several halogenated flame retardants (FRs), nine brominated diphenyls 
      ethers (BDEs) and seven non-BDE FRs, was developed and validated. The optimised 
      procedure is based on polydimethylsiloxane (PDMS) rods as sorptive extraction 
      material, followed by liquid desorption and gas chromatography coupled to 
      negative chemical ionisation-mass spectrometry (GC-NCI-MS) determination, 
      rendering an efficient and inexpensive method. The final optimised protocol 
      consists of overnight extraction of 100mL of sample solutions containing 40% MeOH 
      and 4% NaCl, followed by a 15-min sonication-assisted desorption with 300 muL of 
      ethyl acetate, solvent evaporation and GC-NCI-MS analysis. Under these 
      conditions, extraction efficiencies in the 9 to 70% range were obtained, leading 
      to enrichment factors between 108 and 840, detection limits in the range from 0.4 
      to 10 ng L(-1)and RSD values in the 2-23% range. After method validation, 
      different real water samples, including river, ria, sea, landfill leachate, 
      influent and effluent wastewater from an urban sewage treatment plant (STP) and 
      effluent wastewater from a textile industry, were analysed. BDE-47, BDE-99, 
      BDE-100 and BDE-197 were detected in wastewater and landfill leachate samples at 
      concentration levels up to 2887 ng L(-1). Among the non-BDE FRs, bis 
      (2-ethylhexyl)-3,4,5,6-tetrabromo-phthalate (DEHTBP) was detected in surface 
      water samples (sea, river and ria) between 1.3 and 2.2 ng L(-1) and 
      1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) in the landfill leachate (64 ng 
      L(-1)).
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Valls-Cantenys, Carme
AU  - Valls-Cantenys C
AD  - Department of Chemistry, University of Girona, Campus Montilivi, 17071 Girona, 
      Spain.
FAU - Villaverde-de-Saa, Eugenia
AU  - Villaverde-de-Saa E
FAU - Rodil, Rosario
AU  - Rodil R
FAU - Quintana, Jose Benito
AU  - Quintana JB
FAU - Iglesias, Monica
AU  - Iglesias M
FAU - Salvado, Victoria
AU  - Salvado V
FAU - Cela, Rafael
AU  - Cela R
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130210
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Dimethylpolysiloxanes)
RN  - 0 (Flame Retardants)
RN  - 0 (Waste Water)
RN  - 63148-62-9 (baysilon)
SB  - IM
MH  - Chemistry Techniques, Analytical/*methods
MH  - Dimethylpolysiloxanes/*analysis
MH  - Environmental Monitoring/*methods
MH  - Flame Retardants/*analysis
MH  - Gas Chromatography-Mass Spectrometry
MH  - Limit of Detection
MH  - Rivers/*chemistry
MH  - Wastewater/*chemistry
EDAT- 2013/03/19 06:00
MHDA- 2013/09/18 06:00
CRDT- 2013/03/19 06:00
PHST- 2012/11/01 00:00 [received]
PHST- 2013/01/08 00:00 [revised]
PHST- 2013/01/31 00:00 [accepted]
PHST- 2013/03/19 06:00 [entrez]
PHST- 2013/03/19 06:00 [pubmed]
PHST- 2013/09/18 06:00 [medline]
AID - S0003-2670(13)00208-0 [pii]
AID - 10.1016/j.aca.2013.01.059 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2013 Apr 3;770:85-93. doi: 10.1016/j.aca.2013.01.059. Epub 2013 
      Feb 10.