PMID- 23499219
OWN - NLM
STAT- MEDLINE
DCOM- 20130920
LR  - 20221207
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 91
IP  - 7
DP  - 2013 May
TI  - Sulfonamides and tetracyclines in livestock wastewater.
PG  - 888-94
LID - S0045-6535(13)00317-2 [pii]
LID - 10.1016/j.chemosphere.2013.02.027 [doi]
AB  - Antibiotics (sulfonamides and tetracyclines) have attractive increasing attention 
      due to their persistence for a long time, which lead to concern of widespread 
      antibiotic resistant bacteria and resistance genes in the aquatic environment. 
      Investigation of the occurrence and elimination of antibiotics in the wastewater 
      treatment plant (WWTP) effluent is thus imperative. This paper presents the 
      method development of the liquid chromatography-ion-trap mass spectrometer 
      (IT-MS)-time-of-flight mass spectrometer in series (LC-IT-ToF/MS) hybrid 
      technique to determine concentrations of sulfonamides and tetracyclines in the 
      effluent of animal WWTP. Detection limits of the developed method were 22.8, 
      23.0, 25.8, 23.6, and 9.8ngL(-1) for sulfathiazole, sulfamethazine, 
      sulfamethoxazole, oxytetracycline, and chlortetracycline, respectively. Average 
      recovery efficiencies of the method for sulfonamides fortified in effluent 
      samples of ananimal WWTP at 1.0, and 4.0mugL(-1) were 73-95%, and 89-104%, 
      respectively, while that of the method for tetracyclines fortified at 0.4 and 
      4.0mugL(-1) was 76-104%, and 101-107%, respectively. The analysis of effluent of 
      the WWTP showed that more than 90% of analyzed antibiotics were removed by the 
      treatment consisted of biological, a UF membrane, and a coagulation process. The 
      maximum concentrations of sulfonamide and tetracycline in the WWTP were 49.5 and 
      4.1mugL(-1), respectively.
CI  - Copyright (c) 2013 Elsevier Ltd. All rights reserved.
FAU - Kim, Hyunook
AU  - Kim H
AD  - Department of Energy & Environmental System Engineering, The University of Seoul, 
      Seoul 130-743, South Korea. h_kim@uos.ac.kr
FAU - Hong, Youngmin
AU  - Hong Y
FAU - Park, Jae-eun
AU  - Park JE
FAU - Sharma, Virender K
AU  - Sharma VK
FAU - Cho, Sung-il
AU  - Cho SI
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130315
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Sulfonamides)
RN  - 0 (Tetracyclines)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
SB  - IM
MH  - Animal Husbandry
MH  - Animals
MH  - *Livestock
MH  - Sulfonamides/*analysis
MH  - Tetracyclines/*analysis
MH  - Waste Disposal, Fluid
MH  - Wastewater/*chemistry
MH  - Water Pollutants, Chemical/*analysis
EDAT- 2013/03/19 06:00
MHDA- 2013/09/21 06:00
CRDT- 2013/03/19 06:00
PHST- 2012/10/09 00:00 [received]
PHST- 2013/01/28 00:00 [revised]
PHST- 2013/02/11 00:00 [accepted]
PHST- 2013/03/19 06:00 [entrez]
PHST- 2013/03/19 06:00 [pubmed]
PHST- 2013/09/21 06:00 [medline]
AID - S0045-6535(13)00317-2 [pii]
AID - 10.1016/j.chemosphere.2013.02.027 [doi]
PST - ppublish
SO  - Chemosphere. 2013 May;91(7):888-94. doi: 10.1016/j.chemosphere.2013.02.027. Epub 
      2013 Mar 15.