PMID- 23506564
OWN - NLM
STAT- MEDLINE
DCOM- 20140421
LR  - 20130702
IS  - 1520-5851 (Electronic)
IS  - 0013-936X (Linking)
VI  - 47
IP  - 13
DP  - 2013 Jul 2
TI  - Influence of climate and land use change on spatially resolved volatilization of 
      persistent organic pollutants (POPs) from background soils.
PG  - 7052-9
LID - 10.1021/es3048784 [doi]
AB  - The subject of this study is the assessment of the influence of climate and land 
      use change on the potential re-emission of organochlorine pesticides (OCPs) from 
      background and agricultural soils. A deterministic spatially and temporally 
      explicit model of the air-surface exchange was created, fed with distributed data 
      of soil and atmospheric concentrations from real measurements, and run under 
      various scenarios of temperature and land use change for a case study area 
      representative of central European conditions. To describe land use influence, 
      some important features were implemented including effect of plowing, influence 
      of land cover, temperature of soil, and seasonal changes of air layer stability. 
      Results show that volatilization of pesticides from soil largely exceeded dry gas 
      deposition in most of the area. Agricultural soils accounted for more than 90% of 
      the total re-emissions both because of the generally higher soil fugacities 
      (higher loads of chemicals and relatively low organic carbon content), but also 
      due to physical characteristics and land management practices enhancing the 
      dynamics of the exchange. An increase of 1  degrees C in air temperature produced an 
      increase of 8% in the averaged total volatilization flux, however this effect can 
      be neutralized by a change of land use of 10% of the arable lands to grassland or 
      forest, which is consistent with projected land use change in Europe. This 
      suggests that future assessment of climate impact on POP fate and distribution 
      should take into consideration land use aspects.
FAU - Komprda, Jiri
AU  - Komprda J
AD  - RECETOX (Research Centre for Toxic Compounds in the Environment), Kamenice 753/5, 
      CZ-625 00 Brno, Czech Republic. komprda@recetox.muni.cz
FAU - Komprdova, Klara
AU  - Komprdova K
FAU - Sanka, Milan
AU  - Sanka M
FAU - Mozny, Martin
AU  - Mozny M
FAU - Nizzetto, Luca
AU  - Nizzetto L
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130405
PL  - United States
TA  - Environ Sci Technol
JT  - Environmental science & technology
JID - 0213155
RN  - 0 (Air Pollutants)
RN  - 0 (Soil Pollutants)
RN  - 4M7FS82U08 (Dichlorodiphenyl Dichloroethylene)
RN  - 4Z87H0LKUY (Hexachlorobenzene)
SB  - IM
MH  - Air Pollutants/*analysis/chemistry
MH  - Climate
MH  - Czech Republic
MH  - Dichlorodiphenyl Dichloroethylene/*analysis/chemistry
MH  - Environmental Monitoring
MH  - Hexachlorobenzene/*analysis/chemistry
MH  - *Models, Theoretical
MH  - Soil Pollutants/*analysis/chemistry
MH  - Temperature
MH  - Volatilization
EDAT- 2013/03/20 06:00
MHDA- 2014/04/22 06:00
CRDT- 2013/03/20 06:00
PHST- 2013/03/20 06:00 [entrez]
PHST- 2013/03/20 06:00 [pubmed]
PHST- 2014/04/22 06:00 [medline]
AID - 10.1021/es3048784 [doi]
PST - ppublish
SO  - Environ Sci Technol. 2013 Jul 2;47(13):7052-9. doi: 10.1021/es3048784. Epub 2013 
      Apr 5.