PMID- 23536047 OWN - NLM STAT- MEDLINE DCOM- 20140121 LR - 20211021 IS - 1573-0875 (Electronic) IS - 0169-6149 (Print) IS - 0169-6149 (Linking) VI - 43 IP - 2 DP - 2013 Apr TI - Degradation of glycine and alanine on irradiated quartz. PG - 119-27 LID - 10.1007/s11084-013-9328-3 [doi] AB - Recent researches suggest participation of minerals in the formation of life under primordial conditions. Among all of the minerals, quartz seems to be one of the most probable to take part in such processes. However, an external source of energy is needed, e.g. electric discharge. A device simulating the proposed conditions was designed and was used to simulate prebiotic conditions. Investigation of processes occurring during the stimulation of quartz with electric discharge was studied by means of Ultraviolet-visible (UV-VIS) spectroscopy, in order to monitor the generation kinetics of free radicals. Additionally, infrared spectroscopy was applied to identify chemical reaction products created in a solution of alanine or glycine, in the presence of quartz treated with electric discharge. Formation of increased amounts of free radicals, compared to experiments performed without quartz and/or amino acid, is reported, along with identification of possible degradation products of alanine. No synthetic reactions were observed. FAU - Pawlikowski, Maciej AU - Pawlikowski M AD - Laboratory of Biomineralogy, Department of Mineralogy, Petrography and Geochemistry, Faculty of Geology, Geophysics and Environment Protection, AGH-University of Science and Technology, A Mickiewicz 30 Ave, 30-059 Krakow, Poland. FAU - Benko, Aleksandra AU - Benko A FAU - Wrobel, Tomasz P AU - Wrobel TP LA - eng PT - Journal Article DEP - 20130328 PL - Netherlands TA - Orig Life Evol Biosph JT - Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life JID - 8610391 RN - 0 (Free Radicals) RN - 14808-60-7 (Quartz) RN - OF5P57N2ZX (Alanine) RN - TE7660XO1C (Glycine) SB - IM MH - Alanine/*chemistry MH - Free Radicals/chemistry MH - Glycine/*chemistry MH - Kinetics MH - Quartz/*radiation effects MH - Spectrophotometry, Ultraviolet MH - Spectroscopy, Fourier Transform Infrared PMC - PMC3676737 EDAT- 2013/03/29 06:00 MHDA- 2014/01/22 06:00 PMCR- 2013/03/28 CRDT- 2013/03/29 06:00 PHST- 2013/01/20 00:00 [received] PHST- 2013/03/01 00:00 [accepted] PHST- 2013/03/29 06:00 [entrez] PHST- 2013/03/29 06:00 [pubmed] PHST- 2014/01/22 06:00 [medline] PHST- 2013/03/28 00:00 [pmc-release] AID - 9328 [pii] AID - 10.1007/s11084-013-9328-3 [doi] PST - ppublish SO - Orig Life Evol Biosph. 2013 Apr;43(2):119-27. doi: 10.1007/s11084-013-9328-3. Epub 2013 Mar 28.