PMID- 23582023 OWN - NLM STAT- MEDLINE DCOM- 20131111 LR - 20131121 IS - 1520-5827 (Electronic) IS - 0743-7463 (Linking) VI - 29 IP - 17 DP - 2013 Apr 30 TI - Self-assembly of anionic gemini surfactant: fluorescence resonance energy transfer and simulation study. PG - 5132-7 LID - 10.1021/la304980r [doi] AB - The interaction of dyes with a sulfonated Gemini surfactant was investigated in aqueous solution using Forster resonance energy transfer with acridine orange (AO) as a donor and rhodamine B (RhB) as an acceptor. Surface tension results showed that AO and RhB have different effects on the self-assembly of the Gemini surfactant, with AO giving a higher critical micelle concentration (cmc) and lower surface tension, while the opposite was observed for RhB. Energy transfer from AO to RhB was observed in the presence of the surfactant, and the energy transfer efficiency initially improved with increased surfactant concentration but then decreased significantly when the surfactant reached a higher concentration due to the formation of larger aggregates, which increased the average distance between AO and RhB. Dynamic light scattering demonstrated the existence of these large aggregates. Moreover, simulations using dissipative particle dynamics supported the experimental results. FAU - Liu, Lijuan AU - Liu L AD - School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People's Republic of China. FAU - Fei, Xuening AU - Fei X FAU - Zhu, Sen AU - Zhu S FAU - Yu, Lu AU - Yu L FAU - Zhang, Baolian AU - Zhang B LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20130422 PL - United States TA - Langmuir JT - Langmuir : the ACS journal of surfaces and colloids JID - 9882736 RN - 0 (Anions) RN - 0 (Fluorescent Dyes) RN - 0 (Micelles) RN - 0 (Rhodamines) RN - 0 (Surface-Active Agents) RN - F30N4O6XVV (Acridine Orange) RN - K7G5SCF8IL (rhodamine B) SB - IM MH - Acridine Orange/chemistry MH - Anions/chemical synthesis/chemistry MH - *Fluorescence Resonance Energy Transfer MH - Fluorescent Dyes/*chemistry MH - Hydrodynamics MH - Micelles MH - *Molecular Dynamics Simulation MH - Molecular Structure MH - Rhodamines/chemistry MH - Surface Tension MH - Surface-Active Agents/*chemical synthesis/chemistry EDAT- 2013/04/16 06:00 MHDA- 2013/11/12 06:00 CRDT- 2013/04/16 06:00 PHST- 2013/04/16 06:00 [entrez] PHST- 2013/04/16 06:00 [pubmed] PHST- 2013/11/12 06:00 [medline] AID - 10.1021/la304980r [doi] PST - ppublish SO - Langmuir. 2013 Apr 30;29(17):5132-7. doi: 10.1021/la304980r. Epub 2013 Apr 22.