PMID- 23582907 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20131118 LR - 20130426 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 400 DP - 2013 Jun 15 TI - Comparative study of nanocrystalline titanium dioxide obtained through sol-gel and sol-gel-hydrothermal synthesis. PG - 31-40 LID - S0021-9797(13)00245-2 [pii] LID - 10.1016/j.jcis.2013.03.019 [doi] AB - TiO2 particles were prepared by sol-gel method alone and by sol-gel method combined with hydrothermal treatment. The structural and photocatalytic properties of the two series of photocatalysts were compared. XRD studies revealed that rutilization was faster in the series of photocatalysts, which had been additionally subjected to a hydrothermal process (SG-HT). The hydrothermally treated photocatalysts also displayed a higher specific surface area than those which had only been synthesized using the sol-gel process (SG) and subjected to low calcination temperatures of up to 873 K, while this tendency was inverted at higher temperatures. In accordance with the above observation, the hydrothermally treated series of photocatalysts had a lower particle size than the SG series calcined immediately after the sol-gel process up to 873 K, with this relation being inverted for the highest two temperatures which were studied (973 K and 1023 K) and which saw the commencement of rutilization. Increases in average particle size were observed for both series, with a polyhedral morphology seen as calcination temperature rose. FTIR studies highlighted the presence of the band at 2351 cm(-1) in the SG-HT photocatalysts, characteristic of surface-adsorbed CO2. This was not seen in the SG or P25 photocatalysts. In terms of photoreactivity, the best photocatalyst in the SG-HT series was that calcined at 923 K and in the SG series at 1023 K (SG-1023). Comparing these two photocatalysts and the commercial P25 photocatalyst, SG-1023 was found to be the most photoactive in both the photodegradation and the mineralization of phenol. CI - Copyright (c) 2013 Elsevier Inc. All rights reserved. FAU - Seck, E I AU - Seck EI AD - Grupo de Fotocatalisis y Espectroscopia Aplicada al Medioambiente-FEAM (Unidad Asociada al Instituto de Ciencias de Materiales de Sevilla, CSIC), CIDIA-Departamento de Quimica, Universidad De Las Palmas De Gran Canaria, Las Palmas de Gran Canaria, Spain. seck36@yahoo.fr FAU - Dona-Rodriguez, J M AU - Dona-Rodriguez JM FAU - Pulido Melian, E AU - Pulido Melian E FAU - Fernandez-Rodriguez, C AU - Fernandez-Rodriguez C FAU - Gonzalez-Diaz, O M AU - Gonzalez-Diaz OM FAU - Portillo-Carrizo, D AU - Portillo-Carrizo D FAU - Perez-Pena, J AU - Perez-Pena J LA - eng PT - Journal Article DEP - 20130326 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 EDAT- 2013/04/16 06:00 MHDA- 2013/04/16 06:01 CRDT- 2013/04/16 06:00 PHST- 2013/02/02 00:00 [received] PHST- 2013/03/14 00:00 [revised] PHST- 2013/03/15 00:00 [accepted] PHST- 2013/04/16 06:00 [entrez] PHST- 2013/04/16 06:00 [pubmed] PHST- 2013/04/16 06:01 [medline] AID - S0021-9797(13)00245-2 [pii] AID - 10.1016/j.jcis.2013.03.019 [doi] PST - ppublish SO - J Colloid Interface Sci. 2013 Jun 15;400:31-40. doi: 10.1016/j.jcis.2013.03.019. Epub 2013 Mar 26.