PMID- 23593881
OWN - NLM
STAT- MEDLINE
DCOM- 20140728
LR  - 20231213
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 30
IP  - 12
DP  - 2012 Dec
TI  - [Fast screening ninety-six pesticides in six kinds of agricultural products by 
      high performance liquid chromatography-quadrupole/electrostatic field orbit trap 
      high-resolution mass spectrometry].
PG  - 1246-52
AB  - A high-throughput method for the determination of 96 pesticides in six kinds of 
      agricultural products by liquid chromatography-quadrupole/electrostatic field 
      orbit trap high-resolution mass spectrometry was developed. After extraction with 
      0.1% acetic acid in acetonitrile solution and concentration, dispersive 
      solid-phase extraction was further utilized to reduce the matrix interference. 
      The chromatographic analysis was performed on a C18 column with methanol and 5 
      mmol/L ammonium acetate solution as the mobile phases with a gradient elution 
      program. The 96 pesticide residues were analyzed in switching positive and 
      negative modes at the same time. With the optimized mass resolution, accurate 
      mass-to-charge ratio extraction of the target pesticide compounds in full scan 
      mode could eliminate matrix interference effectively. Two-stage 
      threshold-triggered full mass scan mode was utilized to further improve the 
      accuracy of qualitative analysis. The linear ranges of all the 96 pesticides were 
      from 1 microg/L to 200 microg/L with correlation coefficients greater than 0.99. 
      By detecting spiked samples, the detection limits were 5 microg/kg for all the 
      residues and the recoveries were in the range of 58% - 105% with the relative 
      standard deviations (RSDs) between 8.8% and 18.3%.
FAU - Wu, Bin
AU  - Wu B
AD  - Animal, Plant and Food Inspection Center of Jiangsu Entry-Exit Inspection and 
      Quarantine Bureau, Nanjing 20001, China.
FAU - Ding, Tao
AU  - Ding T
FAU - Liu, Han
AU  - Liu H
FAU - Chen, Huilan
AU  - Chen H
FAU - Zhao, Zengyun
AU  - Zhao Z
FAU - Zhang, Rui
AU  - Zhang R
FAU - Shen, Chongyu
AU  - Shen C
LA  - chi
PT  - English Abstract
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Pesticide Residues)
SB  - IM
MH  - *Chromatography, High Pressure Liquid
MH  - Edible Grain/chemistry
MH  - Food Contamination/analysis
MH  - *Mass Spectrometry
MH  - Pesticide Residues/*analysis
MH  - Solanum tuberosum/*chemistry
MH  - Glycine max/*chemistry
MH  - Vegetables/chemistry
EDAT- 2013/04/19 06:00
MHDA- 2014/07/30 06:00
CRDT- 2013/04/19 06:00
PHST- 2013/04/19 06:00 [entrez]
PHST- 2013/04/19 06:00 [pubmed]
PHST- 2014/07/30 06:00 [medline]
AID - 10.3724/sp.j.1123.2012.07014 [doi]
PST - ppublish
SO  - Se Pu. 2012 Dec;30(12):1246-52. doi: 10.3724/sp.j.1123.2012.07014.