PMID- 23601280
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20131108
LR  - 20130422
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 776
DP  - 2013 May 7
TI  - Preparation and examination of monolithic in-needle extraction (MINE) device for 
      the direct analysis of liquid samples.
PG  - 50-6
LID - S0003-2670(13)00362-0 [pii]
LID - 10.1016/j.aca.2013.03.022 [doi]
AB  - Combination of extraction and chromatographic techniques opens NEW possibilities 
      in sample preparation area. Macroporous poly(styrene-divinylbenzene) (PS-DVB) 
      monoliths were prepared by in situ polymerization in stainless steel needles. The 
      surface of stainless steel needle was modified earlier by the silane coupling 
      agent. Monolithic materials located inside needles were used as the in-needle 
      extraction device. Scanning electron microscope (SEM) images were obtained for 
      nine monoliths. Spectra of prepared materials were also performed with the use of 
      two techniques: Attenuated Total Reflectance (ATR) and Fourier Transform Infrared 
      Spectroscopy (FTIR). The new monolithic in-needle extraction (MINE) devices were 
      used in the preparation of a series of test water samples for chromatographic 
      analysis. The extraction of phenolic compounds from water samples was carried out 
      by pumping liquid samples through the MINE device. Obtained results indicate a 
      high efficiency of in-needle extraction systems based on monolithic materials. 
      Breakthrough volume and the sorption efficiency of prepared monolithic in-needle 
      extraction devices were determined experimentally. The achieved recovery was 
      close to 90%, and determined LOQ values varied between 0.4 and 6 mug.
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Pietrzynska, Monika
AU  - Pietrzynska M
AD  - Poznan University of Technology, Institute of Chemical Technology and 
      Engineering, Poznan, Poland. monikapietrzynska@gmail.com
FAU - Voelkel, Adam
AU  - Voelkel A
FAU - Bielicka-Daszkiewicz, Katarzyna
AU  - Bielicka-Daszkiewicz K
LA  - eng
PT  - Journal Article
DEP - 20130325
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
EDAT- 2013/04/23 06:00
MHDA- 2013/04/23 06:01
CRDT- 2013/04/23 06:00
PHST- 2013/01/29 00:00 [received]
PHST- 2013/02/28 00:00 [revised]
PHST- 2013/03/03 00:00 [accepted]
PHST- 2013/04/23 06:00 [entrez]
PHST- 2013/04/23 06:00 [pubmed]
PHST- 2013/04/23 06:01 [medline]
AID - S0003-2670(13)00362-0 [pii]
AID - 10.1016/j.aca.2013.03.022 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2013 May 7;776:50-6. doi: 10.1016/j.aca.2013.03.022. Epub 2013 
      Mar 25.