PMID- 23623120 OWN - NLM STAT- MEDLINE DCOM- 20131203 LR - 20151119 IS - 1873-0191 (Electronic) IS - 0928-4931 (Linking) VI - 33 IP - 5 DP - 2013 Jul 1 TI - Beta tricalcium phosphate ceramics with controlled crystal orientation fabricated by application of external magnetic field during the slip casting process. PG - 2967-70 LID - S0928-4931(13)00186-0 [pii] LID - 10.1016/j.msec.2013.03.024 [doi] AB - Beta tricalcium phosphate (beta-TCP) is a resorbable bioceramic that has hitherto been utilized in the medical field. Since it crystallizes in the anisotropic hexagonal system, properties such as chemical and physical ones are expected to depend on its crystal axis direction and/or on its crystal plane (anisotropy). Control of crystal orientation is thus important when used in polycrystalline form. Meanwhile, application of a strong magnetic field has been found to be a promising technique to control crystal orientation of anisotropic shape or structured crystals. In this work, we attempted to fabricate beta-TCP ceramics with controlled crystal orientation by applying an external magnetic field during the slip casting process and subsequently sintering them at 1050 degrees C, below the beta-alpha transition temperature. Application of a vertical magnetic field increased intensities of planes perpendicular to c-plane on the top surface, while a horizontal one with simultaneous mechanical mold rotation decreased it. These results indicated that crystal orientation of beta-TCP ceramics were successfully controlled by the external magnetic field and together that the magnetic susceptibility of beta-TCP is chi(c[perpendicular])>chi(c//). CI - Copyright (c) 2013 Elsevier B.V. All rights reserved. FAU - Hagio, Takeshi AU - Hagio T AD - Division of Materials Science and Engineering, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan. bb_nba-dreamer1@katch.ne.jp FAU - Yamauchi, Kazushige AU - Yamauchi K FAU - Kohama, Takenori AU - Kohama T FAU - Matsuzaki, Toshiya AU - Matsuzaki T FAU - Iwai, Kazuhiko AU - Iwai K LA - eng PT - Journal Article DEP - 20130323 PL - Netherlands TA - Mater Sci Eng C Mater Biol Appl JT - Materials science & engineering. C, Materials for biological applications JID - 101484109 RN - 0 (Calcium Phosphates) RN - 0 (beta-tricalcium phosphate) SB - IM MH - Calcium Phosphates/*chemistry MH - *Ceramics MH - Crystallography, X-Ray MH - *Magnetic Fields MH - Materials Testing MH - Microscopy, Electron, Scanning EDAT- 2013/04/30 06:00 MHDA- 2013/12/16 06:00 CRDT- 2013/04/30 06:00 PHST- 2013/01/01 00:00 [received] PHST- 2013/03/10 00:00 [revised] PHST- 2013/03/14 00:00 [accepted] PHST- 2013/04/30 06:00 [entrez] PHST- 2013/04/30 06:00 [pubmed] PHST- 2013/12/16 06:00 [medline] AID - S0928-4931(13)00186-0 [pii] AID - 10.1016/j.msec.2013.03.024 [doi] PST - ppublish SO - Mater Sci Eng C Mater Biol Appl. 2013 Jul 1;33(5):2967-70. doi: 10.1016/j.msec.2013.03.024. Epub 2013 Mar 23.